Synthesis and characterization of Pd-II-methyl complexes with N-heterocyclic carbene-amine ligands

Warsink S; de Boer SY; Jongens LM; Fu CF; Liu ST; Chen JT; Lutz M; Spek AL; Elsevier CJ

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Synthesis and characterization of Pd-II-methyl complexes with N-heterocyclic carbene-amine ligands

机译：具有N-杂环卡宾-胺配体的Pd-II-甲基配合物的合成与表征

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A number of palladium(II) complexes with a heteroditopic NHC-amine ligand and their precursor silver(I) carbene complexes have been efficiently prepared and their structural features have been investigated. The heteroditopic coordination of this ligand class was unequivocally shown by NMR-spectroscopy and X-ray crystallographic analysis. The neutral and cationic cis-methyl-palladium(NHC) complexes are not prone to reductive elimination, which is normally a major degenerative pathway for this type of complex. In contrast, under carbon monoxide atmosphere rapid reductive elimination of the acyl-imidazolium salt was observed.

机译：已经有效地制备了许多具有异位NHC-胺配体的钯（II）配合物及其前体银（I）卡宾配合物，并对其结构特征进行了研究。通过NMR谱和X射线晶体学分析明确显示了该配体类别的异位配位。中性和阳离子的顺式-甲基-钯（NHC）配合物不易于还原消除，这通常是这类配合物的主要变性途径。相反，在一氧化碳气氛下，观察到了酰基咪唑鎓盐的快速还原消除。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第35期|共7页
作者
Warsink S; de Boer SY; Jongens LM; Fu CF; Liu ST; Chen JT; Lutz M; Spek AL; Elsevier CJ;
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正文语种 eng
中图分类化学;
关键词
COORDINATION CHEMISTRY; PALLADIUM COMPLEXES; CRYSTAL-STRUCTURES;

机译：配位化学;钯络合物;晶体结构;

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1. Synthesis and characterization of Pd-II-methyl complexes with N-heterocyclic carbene-amine ligands [J] . Warsink S, de Boer SY, Jongens LM, Dalton transactions: An international journal of inorganic chemistry . 2009,第35期

机译：具有N-杂环卡宾-胺配体的Pd-II-甲基配合物的合成与表征
2. Dinuclear gold(I) and gold(III) complexes of bridging functionalized bis(N-heterocyclic carbene) ligands: synthesis, structural, spectroscopic and electrochemical characterizations [J] . Dominique FJBD, Gornitzka H, Sournia-Saquet A, Dalton transactions: An international journal of inorganic chemistry . 2009,第2期

机译：桥接功能化双（N-杂环卡宾）配体的双核金（I）和金（III）配合物：合成，结构，光谱和电化学表征
3. Synthesis, characterization, and catalytic activity of half-sandwich ruthenium complexes with pyridine/phenylene bridged NHC = E (NHC = N-heterocyclic carbene, E = S, Se) ligands [J] . Jia Wei-Guo, Du Teng-Teng, Gao Li-Li, Applied Organometallic Chemistry . 2020,第7期

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4. Synthesis of Phenylpyridine Iridium(III) Complexes with N-Heterocyclic Carbene as Ancillary Ligands [C] . N H A Bain, N M Ali, Y Juahir International Fundamentum Science Symposium . 2019

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5. Synthesis, characterization, and reactivity of manganese(II) complexes containing N-heterocyclic carbene ligands [D] . Krishnan, Venkateswaran Mahesh 2013

机译：含N-杂环卡宾配体的锰（II）配合物的合成，表征和反应活性
6. Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization [O] . Zhenwu Ouyang, Jingzhen Du, Lei Wang, -1

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7. Synthesis and structural characterization of palladium(II) complexes of chiral bidentate N-heterocyclic carbene-quinoline ligands [O] . Erica L. Ingalls, G. Andrew Holtzen, Werner Kaminsky, 2017

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8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Synthesis and characterization of Pd-II-methyl complexes with N-heterocyclic carbene-amine ligands

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