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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The first observation of azo-hydrazone and cis-trans tautomerisms for disperse yellow dyes and their nickel(ii) and copper(ii) complexes
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The first observation of azo-hydrazone and cis-trans tautomerisms for disperse yellow dyes and their nickel(ii) and copper(ii) complexes

机译:偶氮-和顺反互变异构体用于分散黄色染料及其镍(ii)和铜(ii)配合物的初步观察

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摘要

Azo-hydrazone and cis-trans tautomerisms have been firstly observed between two disperse yellow dyes (cis/trans-HL_1 and cis-HL_2) and three neutral dye-metal complexes (one mononuclear Ni~(II) complex 3 and two Cu~(II) coordination polymers 4 and 5 formulated as [Ni(trans-L_1)_2(CH_3OH)_2] ·2H_2O, [Cu(cis-L_1)_2]_n and [Cu(L_3)(H_2O)]_n).
机译:首先在两种分散的黄色染料(顺式/反式HL_1和顺式HL_2)与三种中性染料-金属配合物(一种单核Ni〜(II)配合物3和两种Cu〜()之间观察到偶氮hydr和顺反互变异构现象。 II)配制成[Ni(反式-L_1)_2(CH_3OH)_2]·2H_2O,[Cu(顺式-L_1)_2] _n和[Cu(L_3)(H_2O)] _ n的配位聚合物4和5。

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