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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Toward design of multiple-property inorganic-organic hybrid compounds based on face-sharing octahedral iodoplumbate chains
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Toward design of multiple-property inorganic-organic hybrid compounds based on face-sharing octahedral iodoplumbate chains

机译:基于面共享八面体碘铅链的多元无机-有机杂化化合物的设计

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摘要

In this review article, we have illustrated the strategies developed to achieve inorganic-organic hybrid compounds with technologically important physical properties. A series of target inorganic-organic hybrid compounds have been accomplished by incorporating the functional organic components (with a large hyperpolarizability and luminophore Schiff base cation) into the highly polarizable one-dimensional (1-D) iodoplumbate chain network. The effect of substituent features in the phenyl ring of the Schiff base cation on its molecular conformation as well as the crystal packing structure of the hybrid compound will be discussed and the multiple physical properties (ferroelectricity, NLO and multiple band emission) will also be mentioned.
机译:在这篇评论文章中,我们说明了为获得具有技术上重要的物理性质的无机-有机杂化化合物而开发的策略。通过将功能性有机成分(具有较大的超极化性和发光团席夫碱阳离子)掺入高度可极化的一维(1-D)碘铅链网络中,可以实现一系列目标无机-有机杂化化合物。将讨论席夫碱阳离子苯环中取代基的特性对其分子构象以及杂化化合物的晶体堆积结构的影响,还将提及多种物理性质(铁电,NLO和多能带发射) 。

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