Unprecedented copper(i)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine

Wen T.; Li M.; Zhou X.-P.; Li D.

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Unprecedented copper(i)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine

机译：基于2-氰基嘧啶的前所未有的铜（i）催化原位双环加成反应

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The solvothermal in situ double cycloaddition reaction of 2-cyanopyrimidine, Cu2O and NaN3 with aqueous ammonia additive generated a two dimensional copper(i) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4-triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.

机译：2-氰基嘧啶，Cu2O和NaN3与氨水的溶剂热原位双环加成反应生成了二维的铜（i）配位聚合物，带有5-嘧啶基-四唑酸酯，3,5-双嘧啶基-1,2,4-三唑酸酯和氰基作为配体。可以调节该反应以产生仅基于四唑酸酯或1,2,4-三唑酸酯配体的二维配位聚合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2011年第21期|共3页
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Wen T.; Li M.; Zhou X.-P.; Li D.;
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1. Unprecedented copper(i)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine [J] . Wen T., Li M., Zhou X.-P., Dalton transactions: An international journal of inorganic chemistry . 2011,第21期

机译：基于2-氰基嘧啶的前所未有的铜（i）催化原位双环加成反应
2. Dendritic phosphoramidite ligands for Rh-catalyzed [2 + 2 + 2] cycloaddition reactions: unprecedented enhancement of enantiodiscriminationf [J] . Lidia Garcia, Anna Roglans, Regis Laurent, Chemical Communications . 2012,第74期

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4. Synthesis of 1,2,4-Azadiphosphole Derivatives Based on Vanadium-Catalyzed 2+2+1 Cycloaddition Reactions of Phosphaalkynes with Azobenzenes [C] . Wenbin Liang, Kazunari Nakajima, Yoshiaki Nishibayashi 日本化学会春季年会講演予稿集 . 2018

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Unprecedented copper(i)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine

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