Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: New organometallic octupoles with large hyperpolarizabilities

Trujillo A.; Veillard R.; Argouarch G.; Roisnel T.; Singh A.; Ledoux I.; Paul F.

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Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: New organometallic octupoles with large hyperpolarizabilities

机译：富电子的Fe（ii）和Ru（ii）乙炔化物络合物官能化的三芳基1,3,5-三嗪烷-2,4,6-三酮：具有超高极化性的新型有机金属八极

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The synthesis and study of a series of trinuclear organometallic triaryl-1,3,5-triazinane-2,4,6-triones functionalized by d ~6- transition metal acetylides complexes at their periphery are reported. Remarkably large hyperpolarizabilities, far superior to those of related purely organic derivatives, are measured by hyper-Rayleigh scattering (HRS) for these new octupolar chromophores.

机译：报道了一系列由d〜6-过渡金属乙炔配合物官能化的三核有机金属三芳基-1,3,5-三嗪烷-2,4,6-三酮的合成和研究。对于这些新的八极生色团，通过超瑞利散射（HRS）测量了非常大的超极化能力，远远优于相关的纯有机衍生物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第25期|共3页
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Trujillo A.; Veillard R.; Argouarch G.; Roisnel T.; Singh A.; Ledoux I.; Paul F.;
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1. Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: New organometallic octupoles with large hyperpolarizabilities [J] . Trujillo A., Veillard R., Argouarch G., Dalton transactions: An international journal of inorganic chemistry . 2012,第25期

机译：富电子的Fe（ii）和Ru（ii）乙炔化物络合物官能化的三芳基1,3,5-三嗪烷-2,4,6-三酮：具有超高极化性的新型有机金属八极
2. DIFFERENTIAL CATALYTIC BEHAVIOUR OF Ru(III),Os(VIII)AND Mn(II)IN THE OXIDATION OF D-GLUCOSE BY 1,3,5-TRICHLORO-1,3,5-TRIAZINE-2,4,6-TRIONE [J] . N.MADHAVI, B.SYAMA SUNDAR, P.S.RADHAKRISHNAMURTI Oxidation Communications . 2006,第2期

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4. Synthesis and Catalytic Study of Magnetic Separable Catalyst: M(Salen)-Functionalized Fe_3O_4 Polymer Composite Materials (M = Ru(III), Cu(II), Fe(III)) [C] . Hao-Yu Shen, Sheng-Dong Pan, Fang Fang International Conference on Manufacturing Science and Engineering . 2011

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6. Photorelease of Pyridyl Esters in Organometallic Ru(II) Arene Complexes [O] . Abraha Habtemariam, Claudio Garino, Emmanuel Ruggiero, 2015

机译：有机金属Ru（II）芳烃配合物中的吡啶酯的光释放
7. Donor-substituted triaryl-1,3,5-triazinanes-2,4,6-triones: octupolar NLO-phores with a remarkable transparency-nonlinearity trade-off [O] . Argouarch, Gilles, Veillard, Romain, Roisnel, Thierry, 2011

机译：供体取代的三芳基-1,3,5-三嗪-2,4,6-三酮：具有显着的透明度-非线性折衷的八极NLO-phores
8. Results of a Local Lymph Node Assay in Mice (LLNA/IMDS) with Toluene Diisocyanate based adduct in Organic Solvent (TDI Trimer) 1,3,5-Triazine- 2,4,6(1H,3H,5H)-trione, 1,3,5-tris(3-isocya natomethylphenyl). [R] . 2011

机译：基于甲苯二异氰酸酯的有机溶剂加成物（TDI三聚体）1,3,5-三嗪-2,4,6（1H，3H，5H） - 三酮，1小鼠局部淋巴结检测结果（LLNa / ImDs），3,5-三（3-isocya natomethylphenyl）。

Triaryl-1,3,5-triazinane-2,4,6-triones functionalized with electron-rich Fe(ii) and Ru(ii) acetylide complexes: New organometallic octupoles with large hyperpolarizabilities

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