Hydrogen activation by 2-boryl-N,N-dialkylanilines: A revision of Piers' ansa-aminoborane

Chernichenko K.; Nieger M.; Leskel? M.; Repo T.

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Hydrogen activation by 2-boryl-N,N-dialkylanilines: A revision of Piers' ansa-aminoborane

机译：2-硼基-N，N-二烷基苯胺对氢的活化作用：对Piers's ansa-aminoborane的修正

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Two 2-[bis(pentafluorophenyl)boryl]-N,N-dialkylanilines reported here exemplify a new class of intramolecular frustrated B/N Lewis pairs. A structure closely related to this class structure was synthesized in 2003 by Piers et al. but was unable to activate H _2. The new aminoboranes can activate hydrogen at near ambient conditions; besides, one of them can hydrogenate imines and enamines in a catalytic fashion demonstrating the validity of the original Piers' approach to hydrogen activation with ansa-aminoboranes.

机译：此处报道的两个2- [双（五氟苯基）硼基] -N，N-二烷基苯胺是一类新型的分子内受阻的B / N Lewis对。 Piers等人在2003年合成了与此类结构密切相关的结构。但无法激活H _2。新的氨基硼烷可以在接近环境条件下活化氢;此外，它们中的一种可以催化方式氢化亚胺和烯胺，证明了最初的Piers方法用ansa-氨基硼烷进行氢活化的有效性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第30期|共4页
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Chernichenko K.; Nieger M.; Leskel? M.; Repo T.;
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1. Hydrogen activation by 2-boryl-N,N-dialkylanilines: A revision of Piers' ansa-aminoborane [J] . Chernichenko K., Nieger M., Leskel? M., Dalton transactions: An international journal of inorganic chemistry . 2012,第30期

机译：2-硼基-N，N-二烷基苯胺对氢的活化作用：对Piers's ansa-aminoborane的修正
2. Nuclear spin hyperpolarization with ansa-aminoboranes: a metal-free perspective for parahydrogen-induced polarization [J] . Zhivonitko Vladimir V., Sorochkina Kristina, Chernichenko Konstantin, Physical chemistry chemical physics: PCCP . 2016,第40期

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机译：硼基介导的钴的可逆H_2活化：催化加氢，脱氢和转移加氢

Hydrogen activation by 2-boryl-N,N-dialkylanilines: A revision of Piers' ansa-aminoborane

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