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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Photoinduced energy transfer processes in hybrid organic-inorganic multichromophoric arrays arranged on a truxene-based platform
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Photoinduced energy transfer processes in hybrid organic-inorganic multichromophoric arrays arranged on a truxene-based platform

机译:在基于丁烯的平台上混合的有机-无机多发色阵列中的光诱导能量转移过程

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摘要

The synthesis, photophysical characterization and energy-transfer features of a series of hybrid truxene derivatives peripherally decorated with inorganic Os-containing polypyridine units and organic Bodipy dyes are reported. The photoactive terminal units are coupled to the central truxene scaffold by rigid ethynyl linkers in a star-shaped arrangement. The absorption range widely covers the UV-Vis spectrum and the Os ~3MLCT or the Bodipy triplet act as final collectors of the absorbed energy.
机译:报道了一系列杂化的芳族戊二烯衍生物的合成,光物理性质和能量转移特征,这些杂合的戊二烯衍生物被无机含Os的聚吡啶单元和有机Bodipy染料外围修饰。光敏末端单元通过刚性乙炔基连接体以星形排列的方式连接至中心戊烯骨架。吸收范围广泛涵盖了紫外-可见光谱,Os〜3MLCT或Bodipy三重态充当了吸收能量的最终收集器。

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