Heteroscorpionate ligands based on bis(pyrazol-l-yl)methane:design and coordination chemistry

A.Otero; J.Fernandez-Baeza; A.Antinolo; A.Lara-Sanchez

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Heteroscorpionate ligands based on bis(pyrazol-l-yl)methane:design and coordination chemistry

机译：基于双（吡唑-1-基）甲烷的异蝎子配体：设计和配位化学

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Scorpionates represent one of the most versatile types of tridentate ligand that can coordinate to a wide variety of elements, e.g. from early to late transition metals, and the coordination chemistry of these systems has developed greatly in recent years. This Perspective gives an account of studies on the following aspects: (1) the preparative methods for a new class of heteroscorpionate [RR'C(pz)_2] ligand derived from bis(pyrazol-l-yl)methane and (2) the description of metal complexes containing these ligands, examples of which incorporate a range of different metals from the Periodic Table.

机译：蝎子代表三齿配体的最通用类型之一，其可以与多种元素例如配体结合。从早期过渡金属到晚期过渡金属，近年来这些系统的配位化学得到了极大的发展。该观点对以下方面进行了研究：（1）新型的由双（吡唑-1-基）甲烷衍生的异蝎形[RR'C（pz）_2]配体的制备方法，（2）含有这些配体的金属配合物的描述，其实例包括元素周期表中一系列不同的金属。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第10期|共12页
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A.Otero; J.Fernandez-Baeza; A.Antinolo; A.Lara-Sanchez;
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1. Heteroscorpionate ligands based on bis(pyrazol-l-yl)methane:design and coordination chemistry [J] . A.Otero, J.Fernandez-Baeza, A.Antinolo, Dalton transactions: An international journal of inorganic chemistry . 2004,第10期

机译：基于双（吡唑-1-基）甲烷的异蝎子配体：设计和配位化学
2. Metal complexes with heteroscorpionate ligands based on the bis(pyrazol-1-yl)methane moiety: Catalytic chemistry [J] . Antonio Otero, Juan Fernandez-Baeza, Agustin Lara-Sanchez, Coordination chemistry reviews . 2013,第11a12期

机译：具有基于双（吡唑-1-基）甲烷部分的杂蝎子配体的金属配合物：催化化学
3. A comparison of the coordination preferences of Zn, Co, and Cd(II) with the heteroscorpionate ligand (2-hydroxy-3-t-butyl-methylphenyl)bis(3,5-dimethylpyrazolyl)methane [J] . Shirin Z., Hammes BS., Warthen CR., Journal of chemical crystallography . 2003,第5a6期

机译：Zn，Co和Cd（II）与异蝎子配体（2-羟基-3-叔丁基-甲基苯基）双（3,5-二甲基吡唑基）甲烷配位偏好的比较
4. In Vivo Coordination Chemistry and Biolocalization of Bis(ligand)oxovanadium(IV) Complexes for Diabetes Treatment [C] . Katherine H. Thompson, Barry D. Liboiron, Graeme R. Hanson, Symposium on Medicinal Inorganic Chemistry . 2005

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5. Coordination chemistry of polytopic, third-generation bis(pyrazolyl)methane ligands [D] . Watson, Russell Patrick 2006

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6. Structural Diversity of Six Coordination Polymers Based on the Designed X-Shaped Ligand 1111-Tetrakis(3-pyridiniourea)methylmethane [O] . Qi-Long Zhang, Qing Yu, Hai-Fang Xie, 2018

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7. New N, N, N-Heteroscorpionates Based on 2, 2-Bis(pyrazolyl)ethanamine and Its Derivatives. Ligands Designed for Probing Supramolecular Interactions [O] . -1

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8. Coordination Chemistry of Divalent Bis(Pentamethylcyclopentadienyl)Lanthanide Complexes with Non-Classical Ligands [R] . Burns, C. J. 1987

机译：二价双（五甲基环戊二烯基）镧系配合物与非经典配体的配位化学

Heteroscorpionate ligands based on bis(pyrazol-l-yl)methane:design and coordination chemistry

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