Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic H-1 NMR, and electrochemical investigations

Tubbs KJ; Szajna E; Bennett B; Halfen JA; Watkins RW; Arif AM; Berreau LM

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Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic H-1 NMR, and electrochemical investigations

机译：单核氮/硫连接的甲醇钴（II）配合物：结构，EPR，顺磁性H-1 NMR和电化学研究

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The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic H-1 NMR, and cyclic voltammetry.

机译：单核氮/硫连接的Co（II）醇盐配合物的第一个例子，是与Co（II）取代的肝醇脱氢酶所观察到的与反应中间体相关的物种，已被分离并通过多种方法进行了表征，包括X射线晶体学， EPR，顺磁性H-1 NMR和循环伏安法。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第16期|共2页
作者
Tubbs KJ; Szajna E; Bennett B; Halfen JA; Watkins RW; Arif AM; Berreau LM;
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正文语种 eng
中图分类无机化学;
关键词
LIVER ALCOHOL-DEHYDROGENASE; ALKOXIDE; CRYSTAL; LIGANDS;

机译：肝脏酒精脱氢酶;烷氧化物;结晶;脂质;

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机译：单核氮/硫连接的甲醇钴（II）配合物：结构，EPR，顺磁性H-1 NMR和电化学研究
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Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: Structural, EPR, paramagnetic H-1 NMR, and electrochemical investigations

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