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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The chemistry of organoimido derivatives of polyoxometalates
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The chemistry of organoimido derivatives of polyoxometalates

机译:多金属氧酸盐的有机亚胺衍生物的化学

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摘要

The chemistry of organoimido derivatives of polyoxometalates (POMs) has received increasing interest. In recent decades, a great development of the synthetic chemistry of organoimido derivatives of POMs using different imido-releasing reagents has taken place, particularly the novel DCC-dehydrating protocol to prepare organoimido derivatives of POMs was developed recently by us and co-workers. Organoimido substituted POMs as valuable building blocks can construct novel nanostructured organic-inorganic hybrid molecular materials in well-developed common organic synthesis methods, such as Pd-catalyzed carbon-carbon coupling and esterification. Therefore, the reactive chemistry of organoimido derivatives of POMs stands for the fascinating future of the chemistry of organoimido derivatives of POMs.
机译:多金属氧酸盐(POM)的有机亚胺衍生物的化学性质受到越来越多的关注。在最近的几十年中,使用不同的亚胺释放试剂的POMs有机亚胺衍生物的合成化学有了很大的发展,特别是我们和同事最近开发了新型的DCC脱水方案来制备POMs的有机亚胺衍生物。有机亚胺基取代的POM作为有价值的构建基块,可以在发达的常见有机合成方法(如Pd催化的碳-碳偶联和酯化)中构建新型的纳米结构有机-无机杂化分子材料。因此,POMs的有机亚胺衍生物的反应化学代表了POMs的有机化学迷人的未来。

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