Water-soluble ruthenium(II)catalysts[RuCl_2(eta~6-arene)-{P(CH_2OH)_3}]for isomerization of allylic alcohols and alkyne hydration

Victorio Cadierno; Pascale Crochet; Sergio E.Garcia-Garrido

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Water-soluble ruthenium(II)catalysts[RuCl_2(eta~6-arene)-{P(CH_2OH)_3}]for isomerization of allylic alcohols and alkyne hydration

机译：水溶性钌（II）催化剂[RuCl_2（η〜6-芳烃）-{P（CH_2OH）_3}]用于烯丙基醇的异构化和炔烃的水合

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The novel water-soluble ruthenium(II)complexes[RuCl_2(eta~6-arene){P(CH_2OH)_3}]2a-c and[RuCl(eta~6-arene){P(CH_2OH)_3}_2][Cl]3a-c have been prepared in high yields by reaction of dimers[{Ru(eta~6-arene)(eta-Cl)Cl}_2](arene = C_6H_6 la,p-cymene Ib,C_6Me6 Ic)with two or four equivalents of P(CH_2OH)_3,respectively.Complexes 2/3a-c are active catalysts in the redox isomerization of several allylic alcohols into the corresponding saturated carbonyl compounds under water-heptane biphasic conditions.Among them,the neutral derivatives[RuCl_2(eta~6-C_6H_6){P(CH_2OH)_3}]2a and[RuCl_2(eta~6-p-cymene){P(CH_2OH)_3}]2b show the highest activities(TOP values up to 600 h~(-1);TON values up to 782).Complexes 2/3a-c also catalyze the hydration of terminal alkynes.

机译：新型水溶性钌（II）络合物[RuCl_2（η〜6-芳烃）{P（CH_2OH）_3}] 2a-c和[RuCl（η〜6-芳烃）{P（CH_2OH）_3} _2] [通过二聚体[{Ru（eta〜6-芳烃）（eta-Cl）Cl} _2]（芳烃= C_6H_6 la，p-cymene Ib，C_6Me6 Ic）与两个二聚体的反应高产率制备Cl] 3a-c化合物4 / 3a-c是分别在水/正庚烷双相条件下将几种烯丙醇氧化还原为相应的饱和羰基化合物中的活性催化剂。 [RuCl_2（eta〜6-C_6H_6）{P（CH_2OH）_3}] 2a和[RuCl_2（eta〜6-对-cymene）{P（CH_2OH）_3}] 2b显示最高的活性（TOP值高达600 h 〜（-1）; TON值高达782）。络合物2 / 3a-c还催化末端炔烃的水合。

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《Dalton transactions: An international journal of inorganic chemistry》 |2004年第21期|共7页
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Victorio Cadierno; Pascale Crochet; Sergio E.Garcia-Garrido;
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1. Water-soluble ruthenium(II)catalysts[RuCl_2(eta~6-arene)-{P(CH_2OH)_3}]for isomerization of allylic alcohols and alkyne hydration [J] . Victorio Cadierno, Pascale Crochet, Sergio E.Garcia-Garrido Dalton transactions: An international journal of inorganic chemistry . 2004,第21期

机译：水溶性钌（II）催化剂[RuCl_2（η〜6-芳烃）-{P（CH_2OH）_3}]用于烯丙基醇的异构化和炔烃的水合
2. Highly water-soluble arene-ruthenium(II) complexes: application to catalytic isomerization of allylic alcohols in aqueous medium [J] . Beatriz Lastra-Barreira, Josefina Diez, Pascale Crochet Green chemistry . 2009,第10期

机译：高水溶性芳烃-钌（II）配合物：在水性介质中烯丙基醇的催化异构化中的应用
3. Enantioselective Isomerization of Primary Allylic Alcohols into Chiral Aldehydes with the tol-binap/dbapen/Ruthenium(II) Catalyst [J] . Noriyoshi Arai, Keisuke Sato, Keita Azuma Angewandte Chemie . 2013,第29期

机译：Tol-binap / dbapen / Ruthenium（II）催化剂将主要烯丙醇对映异构化为手性醛
4. Sequential Process of Isomerization and Meerwein-Ponndorf-Verley-Type Reduction for Efficient Hydrogenation of Allylic Alcohols with Heterogeneous Ruthenium Catalyst [C] . Ju Young KIM, Jung Won KIM Beijing Institute of Technology;China Ordnance Society;International autumn seminar on propellants, explosives and pyrotechnics;Hubei Institute of Aerospace Chemotechnology . 2015

机译：异构化钌催化剂高效异构化烯醇的异构化和Meerwein-Ponndorf-Verley型还原的顺序过程
5. The synthesis and reactivity of allylic alcohols and their derivatives: The synthesis of (Z)-3beta,16alpha-dihydroxy-5,17(20)-pregnadiene 3-pivaloate; the Mitsunobu reaction of 2-cyclohexenols; the europium(III) -catalyzed rearrangement of allylic methoxyacetates. [D] . Shull, Brian Keith. 1991

机译：烯丙醇及其衍生物的合成和反应性：（Z）-3beta，16alpha-dihydroxy-5,17（20）-pregnadiene 3-pivaloate的合成； 2-环己醇的Mitsunobu反应；（（III）催化烯丙基甲氧基乙酸酯的重排。
6. Alkyne–Aldehyde Reductive C–C Coupling through Ruthenium-Catalyzed Transfer Hydrogenation: Direct Regio- and Stereoselective Carbonyl Vinylation to Form Trisubstituted Allylic Alcohols in the Absence of Premetallated Reagents [O] . Joyce C. Leung, Ryan L. Patman, Brannon Sam, -1

机译：炔烃 - 醛还原C-C通过钌催化的转移氢化：直接测定和立体选择性羰基乙烯化在没有预热试剂的情况下形成三取代的烯丙基醇
7. Innentitelbild: Enantioselective Isomerization of Primary Allylic Alcohols into Chiral Aldehydes with the tol-binap/dbapen/Ruthenium(II) Catalyst (Angew. Chem. 29/2013) [O] . Noriyoshi Arai, Keisuke Sato, Keita Azuma, 2013

机译：Innentitelbild：用Tol-Binap / dbapen /钌（II）催化剂（Angew.29 / 2013），初生烯丙基醇对手性醛的映射性异构化成手性醛.29 / 2013）

Water-soluble ruthenium(II)catalysts[RuCl_2(eta~6-arene)-{P(CH_2OH)_3}]for isomerization of allylic alcohols and alkyne hydration

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