A chiral [2]catenane self-assembled from meso-macrocycles of palladium(II)

Burchell TJ; Eisler DJ; Puddephatt RJ

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A chiral [2]catenane self-assembled from meso-macrocycles of palladium(II)

机译：由钯（II）的介观大环自组装的手性[2]环烷

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Reaction of trans-[PdX2(SMe2)(2)] (X = Cl or Br) with the chiral ligand LL = 1,1-binaphthyl-2,2'-(NHC( = O)-3-C5H4N) 2 gave the [2]catenane complexes trans-[{(PdX2)(2)(mu-LL)(2)}(2)], which are formed by self-assembly from 4 units each of trans-PdX2 and LL. The catenation is favored by the formation of multiple hydrogen bonds between the constituent macrocycles (4 x NH...ClPd, 2 x NH...O=C). If the ligand LL is racemic, each macrocycle trans-[ (PdX2)(2)(mu-LL)(2)] is formed in the meso form trans-[(PdX2)(2)(mu-R-LL)(mu-S-LL)] but the resulting [2]catenane is chiral as a direct result of the catenation step. This is the first time that this form of chiral [2]catenane has been observed. The enantiomers of the [2]catenane further self-assemble in the crystalline form, through secondary intermolecular Pd...X bonding, to form a racemic infinite supramolecular polymer of [2]catenanes.

机译：反式-[PdX2（SMe2）（2）]（X = Cl或Br）与手性配体LL = 1,1-双萘基-2,2'-（NHC（= O）-3-C5H4N）2的反应[2] catenane配合物反式-[{（（PdX2）（2）（mu-LL）（2）}（2）]，由反式-PdX2和LL各自由4个单元自组装而成。通过在组成的大环之间形成多个氢键（4 x NH ... ClPd，2 x NH ... O = C）促进串联反应。如果配体LL是外消旋的，则每个大环反式[[（PdX2）（2）（mu-LL）（2）]以内消旋形式形成反式[[（PdX2）（2）（mu-R-LL）（ mu-S-LL）]，但是作为连接步骤的直接结果，所得的[2]环烷是手性的。这是首次观察到这种形式的手性[2]环戊烷。 [2] catenane的对映体通过次级分子间Pd ... X键进一步以结晶形式自组装，形成[2] catenanes的外消旋无限超分子聚合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2005年第2期|共5页
作者
Burchell TJ; Eisler DJ; Puddephatt RJ;
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正文语种 eng
中图分类无机化学;
关键词
REGIOSELECTIVE TEMPLATE SYNTHESIS; COORDINATION RINGS; REVERSIBLE CATENATION; MOLECULAR MACHINES; CATENANES; GOLD(I); COPPER(I); lt; 2gt; CATENANES; INTERLOCKING; INDUCTION;

机译：区域选择性模板合成;配位环;可逆固位;分子机械;类别;金（I）;铜（I）;2类别;联锁;诱导;

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专利

1. A chiral [2]catenane self-assembled from meso-macrocycles of palladium(II) [J] . Burchell TJ, Eisler DJ, Puddephatt RJ Dalton transactions: An international journal of inorganic chemistry . 2005,第2期

机译：由钯（II）的介观大环自组装的手性[2]环烷
2. Tellurium-chlorine secondary interactions in palladium(II) complex of MeOC6H4TeCH2CH2NHCH(CH3)C6H4-2-OH resulting in self-assembled bimolecular aggregates with short palladium-palladium distances [J] . Kumar R, Singh AK, Drake JE, Structural Chemistry . 2007,第2期

机译：MeOC6H4TeCH2CH2NHCH（CH3）C6H4-2-OH的钯（II）配合物中的碲-氯次级相互作用导致钯-钯距离短的自组装双分子聚集体
3. Palladium(II)-directed self-assembly of dynamic donor-acceptor [2]catenanes [J] . Liu Y, Bruneau A, He JM, Organic letters . 2008,第5期

机译：动态供体-受体[2]儿茶酚的钯（II）定向自组装
4. Synthesis of chiral palladium(II) catalysts and their evaluation for enantioselective intramolecular aminopalladation of olefins. [C] . Liene Grigorjeva, Aigars Jirgensons European Symposium on Organic Chemistry . 2009

机译：手性钯（II）催化剂的合成及其对烯烃对映重细胞分子分子氨基酰胺的评价。
5. Part I. Palladium-catalyzed silylstannylations of diynes: Dynamic behavior and functionalization of helically chiral dienes. Part II. Palladium-catalyzed silylstannane additions to epoxyalkynes and their titanium(III)-mediated cyclizations. [D] . Apte, Sandeep D. 2006

机译：第一部分：二炔的钯催化的甲硅烷基锡烷基化：螺旋手性二烯的动态行为和功能化。第二部分钯催化的环氧烷烃硅烷基锡烷的加成反应及其钛（III）介导的环化反应。
6. Chiral Amine Ee Determination Using Self-Assembled Octahedral Fe(II)-Imine Complexes [O] . Justin M. Dragna, Alexandra M. Gade, Lee Tran, -1

机译：使用自组装八面体Fe（II）-亚胺配合物测定手性胺Ee
7. 2Catenanes and inclusion complexes derived from self-assembled rectangular PdII and PtII metallocycles [O] . Alvariño C, Terenzi A, Blanco V, 2012

机译：2自组装的矩形PdII和PtII金属环衍生的儿茶素和包合物

A chiral [2]catenane self-assembled from meso-macrocycles of palladium(II)

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