Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions

Pascu M; Clarkson GJ; Kariuki BM; Hannon MJ

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Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions

机译：通过pi-pi相互作用聚合基于亚胺的金属-超分子体系结构

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The design of supramolecular architectures based on isoquinoline-imine ligand systems is described. The isoquinoline affords an extended pi surface and the use of this surface to obtain self-recognition and consequent pi-pi aggregation is investigated. The approach is effective in that each of four complexes is observed to aggregate through these interactions. Other pi-pi interactions can interfere with the aggregation indicating that a larger pi-surface may be required to obtain complete control over the aggregation of the units.

机译：描述了基于异喹啉-亚胺配体系统的超分子体系结构的设计。异喹啉可提供扩展的pi表面，并研究了该表面用于获得自我识别和pi-pi聚集的作用。该方法是有效的，因为观察到四个复合物中的每一个都通过这些相互作用而聚集。其他pi-pi相互作用可能会干扰聚集，表明可能需要更大的pi表面才能完全控制单元的聚集。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第22期|共8页
作者
Pascu M; Clarkson GJ; Kariuki BM; Hannon MJ;
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正文语种 eng
中图分类无机化学;
关键词
BIS-PYRIDYLIMINE LIGANDS; COORDINATION POLYMERS; STRUCTURAL-CHARACTERIZATION; INEXPENSIVE APPROACH; DINUCLEAR SILVER(I); CRYSTAL-STRUCTURE; SCHIFF-BASE; COMPLEXES; COPPER(I); CHEMISTRY;

机译：BIS-吡啶亚胺类配体;配位聚合物;结构表征;低价方法;银（I）;晶体结构;席夫夫基;络合物;铜（I）;化学性质;

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1. Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions [J] . Pascu M, Clarkson GJ, Kariuki BM, Dalton transactions: An international journal of inorganic chemistry . 2006,第22期

机译：通过pi-pi相互作用聚合基于亚胺的金属-超分子体系结构
2. Luminescent 1D chain of platinum(II)terpyridyl units with p-dithiobenzoquinone organometallic linker:self-aggregation imparted from Pt…Pt/pi-pi interactions [J] . Jamal Moussa, Keith Man-Chung Wong, Lise-Marie Chamoreau Dalton transactions: An international journal of inorganic chemistry . 2007,第32期

机译：对-二硫代苯醌有机金属接头的铂（II）吡啶基单元的发光一维链：Pt…Pt / pi-pi相互作用赋予的自聚集
3. Synthesis and spectroscopic investigation of aggregation through cooperative pi-pi and C-H center dot center dot center dot O interactions in a novel pyrene octaaldehyde derivative [J] . Venkataramana G, Sankararaman S Organic letters . 2006,第13期

机译：新型pyr八醛衍生物中pi-pi和C-H中心点中心点中心点O相互作用的聚集体的合成及光谱研究
4. Cloud architecture for tight interaction with the real world and deep sensor-data aggregation mechanism [C] . Aoki Hidetaka, Shikano Hiroaki, Okuno Michitaka, 2010 International Conference on Software, Telecommunications and Computer Networks . 2010

机译：云架构可与现实世界紧密交互，并具有深度传感器数据聚合机制
5. Synthesis and characterization of self-assembling peptides bearing pi-conjugated subunits to study pi-pi interactions. [D] . Wall, Brian D. 2013

机译：具有pi共轭亚基的自组装肽的合成和表征，以研究pi-pi相互作用。
6. Linear and Nonlinear Dynamic Behavior of Polymer Micellar Assemblies Connected by Metallo-Supramolecular Interactions [O] . Zhi-Chao Yan, Florian J. Stadler, Pierre Guillet, 2019

机译：金属-超分子相互作用连接的聚合物胶束组件的线性和非线性动力学行为
7. Threee substituted(Z)-5-benzylidene-2-thioxothiazolidin-4-ones: hydrogen-bonded dimers that can be effectively isolated or linked into chains either by aromatic pi-pi stacking interactions or by dipolar carbonyl-carbonyl interactions [O] . Delgado, Paula, Quiroga, Jairo, de la Torre, Jose M., 2006

机译：Threee取代的（Z）-5-亚苄基-2-硫代噻唑啉酮-4-酮：氢键二聚体，可以通过芳族pi-pi堆积相互作用或通过偶极羰基-羰基相互作用有效分离或连接成链
8. Pi-Pi Interaction in the Complexes of the Pyridino-18-Crown-6 Host Molecules andAromatic Ammonium Salts as Determined by H NMR Spectroscopy [R] . Wang, T.-M., Bradshaw, J. S., Curtis, J. C., 1993

机译：pyridino-18-Crown-6主体分子和芳香铵盐配合物中的pi-pi相互作用由H NmR谱确定

Aggregation of imine-based metallo-supramolecular architectures through pi-pi interactions

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