Polymeric arrangements of P-Se anions and a first insight into their reactivity

Shi WF; Shafaei-Fallah M; Anson CE; Rothenberger A

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Polymeric arrangements of P-Se anions and a first insight into their reactivity

机译：P-Se阴离子的聚合物排列方式及其对反应性的初步了解

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The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)mu-Se](2) with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P - Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3](2-) or [PhPSe2Se - SeSe2PPh](2-) dianions are observed and the mechanisms of their formation described.

机译：P / Se前体Woollins试剂[PhP（Se）mu-Se]（2）与碱金属盐的反应为合成含P-Se阴离子的金属聚集体提供了新的视角。取决于碱金属硫醇盐，观察到[PhPSe3]（2-）或[PhPSe2Se-SeSe2PPh]（2-）阴离子的聚合物排列，并描述了它们的形成机理。

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《Dalton transactions: An international journal of inorganic chemistry》 |2006年第24期|共5页
作者
Shi WF; Shafaei-Fallah M; Anson CE; Rothenberger A;
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正文语种 eng
中图分类无机化学;
关键词
CRYSTAL-STRUCTURES; METAL-COMPLEXES; PHOSPHORUS; LIGANDS; SALTS; ESTERS; ACIDS;

机译：晶体结构;金属络合物;磷;配体;盐;酯;酸;

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Polymeric arrangements of P-Se anions and a first insight into their reactivity

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