Fixation of atmospheric carbon dioxide by a cadmium(II) macrocyclic complex

Janzen DE; Botros ME; VanDerveer DG; Grant GJ

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Fixation of atmospheric carbon dioxide by a cadmium(II) macrocyclic complex

机译：镉（II）大环配合物固定大气中的二氧化碳

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摘要

A crystal structure showing an unusual trinuclear Cd(II) cluster bridged in mu(3) fashion by a carbonate ligand is reported. The carbonate ion is formed by fixation of atmospheric carbon dioxide from the corresponding cadmium mononuclear complex containing an aza crown ether.

机译：据报道，晶体结构显示了一个不寻常的三核Cd（II）簇，由碳酸盐配体以mu（3）形式桥接。碳酸根离子是通过固定相应的含氮杂冠醚的单核镉络合物中的大气二氧化碳而形成的。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第45期|共6页
作者
Janzen DE; Botros ME; VanDerveer DG; Grant GJ;
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正文语种 eng
中图分类无机化学;
关键词
HYDROXIDE COMPLEX; COPPER(II) COMPLEXES; BIOLOGICAL FUNCTION; CO2 REACTIVITY; RELEVANT; LIGANDS; ANION;

机译：氢氧化物络合物;铜（II）络合物;生物功能;CO2反应性;相关;液体;阴离子;

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1. Fixation of atmospheric carbon dioxide by a cadmium(II) macrocyclic complex [J] . Janzen DE, Botros ME, VanDerveer DG, Dalton transactions: An international journal of inorganic chemistry . 2007,第45期

机译：镉（II）大环配合物固定大气中的二氧化碳
2. Cadmium(II) and copper(II) complexes with imidazole-containing tripodal polyamine ligands: pH and anion effects on carbon dioxide fixation and assembling [J] . Kong LY, Zhu HF, Huang YQ, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第20期

机译：含咪唑的三脚架多胺配体的镉（II）和铜（II）配合物：pH和阴离子对二氧化碳固定和组装的影响
3. Carbon dioxide fixation by zinc(II)complexes with macrocyclic ligand [J] . Zhao-Peng Qi, Shu-An Li, Yong-Qing Huang Inorganic Chemistry Communications . 2008,第8期

机译：具有大环配体的锌（II）配合物固定二氧化碳
4. Synthesis of Macrocyclic Cobalt/Lanthanide Multinuclear Complexes for Copolymerization of An Epoxide with Carbon Dioxide and Study on Its Activity [C] . Hiroki Asaba, Takanori Iwasaki, Haruki Nagae 日本化学会春季年会講演予稿集 . 2018

机译：致癌钴/镧系元素多核复合物的合成与二氧化碳环氧化物共聚及其活性研究
5. Macrocyclic complexes and their use as electrocatalysts for the electrochemical reduction of carbon dioxide [D] . Smith, Caroline. 1995

机译：大环配合物及其作为电化学还原二氧化碳的电催化剂的用途
6. An efficient copper-based magnetic nanocatalyst for the fixation of carbon dioxide at atmospheric pressure [O] . Rakesh Kumar Sharma, Rashmi Gaur, Manavi Yadav, -1

机译：一种用于在大气压下固定二氧化碳的高效铜基磁性纳米催化剂
7. Cadmium(II) and Copper(II) Complexes with Imidazole-Containing Tripodal Polyamine Ligands: pH and Anion Effects on Carbon Dioxide Fixation and Assembling [O] . -1

机译：镉（II）和铜（II）配合物配含咪唑三曲面聚胺配体：pH和阴离子对二氧化碳固定和组装的影响
8. Transition Organometallic Heterobimettalic Microns-Carbon Dioxide and Microns-Format Complexes in Homogeneous Carbon Dioxide Fixation [R] . Cutler, A. R. 1992

机译：均相二氧化碳固定过渡有机金属异二聚体微粒 - 二氧化碳和微米形态复合物

Fixation of atmospheric carbon dioxide by a cadmium(II) macrocyclic complex

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