Asymmetric hydroamination of non-activated carbon-carbon multiple bonds

Aillaud I; Collin J; Hannedouche J; Schulz E

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Asymmetric hydroamination of non-activated carbon-carbon multiple bonds

机译：非活化碳-碳多键的不对称加氢胺化

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The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.

机译：综述了加氢胺化反应催化的碳氮键对映选择性的形成。所有实施例均涉及含有未活化的碳-碳多键的底物，其可通过分子内或分子间反应转化。结构上不同的配合物已经提供了具有高对映选择性的含氮化合物/杂环。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第44期|共14页
作者
Aillaud I; Collin J; Hannedouche J; Schulz E;
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正文语种 eng
中图分类无机化学;
关键词
ENANTIOSELECTIVE INTRAMOLECULAR HYDROAMINATION; ORGANOLANTHANIDE-CATALYZED HYDROAMINATION; SUBSTITUTED (R)-1; 1'-BINAPHTHYL-2; 2'-DIAMIDO LIGANDS; UNPROTECTED AMINO OLEFINS; INTERMOLECULAR HYDROAMINATION; ALKENE HYDROAMINATION; ALKYNE HYDROAMINATION; UNACTIVATED ALKENES; YTTRIUM COMPLEXES; AMIDATE COMPLEXES;

机译：对映选择性分子内加氢;有机酸催化的加氢;取代的（R）-1;1'-联萘-2;2'-二酰胺配体;未保护的氨基烯烃;分子间加氨化;缩合的;缩合的;缩醛的;

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1. Asymmetric hydroamination of non-activated carbon-carbon multiple bonds [J] . Aillaud I, Collin J, Hannedouche J, Dalton transactions: An international journal of inorganic chemistry . 2007,第44期

机译：非活化碳-碳多键的不对称加氢胺化
2. Asymmetric synthesis of beta-hydroxy-beta-trifluoromethylated ketones via in situ generation of trifluoroacetaldehyde and its asymmetric carbon-carbon bond formation reaction with chiral imines in aqueous media [J] . Kazumasa Funabiki, Kazutoshi Hasegawa, Yoshihiro Murase, Journal of Fluorine Chemistry . 2006,第4a5期

机译：通过原位生成三氟乙醛不对称合成β-羟基-β-三氟甲基化酮及其在水介质中与手性亚胺的不对称碳-碳键形成反应
3. Practical asymmetric synthesis of β-hydroxy-β-trifluoromethylated ketones via the first example of the in situ generation of trifluoroacetaldehyde and its successive asymmetric carbon-carbon bond formation reaction with chiral imines [J] . Kazumasa Funabiki, Wataru Hashimoto, Masaki Matsui Chemical Communications . 2004,第18期

机译：通过原位生成三氟乙醛的第一个实例及其与手性亚胺连续发生的不对称碳-碳键形成反应的实例，实际合成β-羟基-β-三氟甲基化酮
4. Catalytic Asymmetric Carbon-Carbon Bond Formation in Water and Air [C] . (missing) International symposium on green chemistry in China . 2002

机译：水和空气中催化不对称碳 - 碳键形成
5. Platinum(II) and gold(I) catalyzed hydroamination of carbon-carbon multiple bonds [D] . Bender, Christopher Franklin 2007

机译：铂（II）和金（I）催化的碳-碳多键加氢胺化
6. The Influence of Carbon-Carbon Multiple Bonds on the Solvolyses of Tertiary Alkyl Halides: a Grunwald-Winstein Analysis [O] . Marina C. Reis, Ruben Elvas-Leitão, Filomena Martins 2008

机译：碳-碳多重键对叔烷基卤化物溶剂化的影响：Grunwald-Winstein分析
7. Enantioselective Hydroalkynylation of Non-Polar Carbon-Carbon Double Bonds: Iridium-Catalyzed Asymmetric Addition Reaction of Terminal Alkyne CH Bonds to Substituted Norbornadienes [O] . Yang Q, Choy PY, Fan B, 2015

机译：非极性碳-碳双键的对映选择性加氢烷基化反应：铱催化末端炔烃CH键与取代的降冰片二烯的不对称加成反应

Asymmetric hydroamination of non-activated carbon-carbon multiple bonds

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