C-H activation motivated by N,N'-diisopropylcarbodiimide within a lutetium complex stabilized by an amino-phosphine ligand

Liu B; Yang Y; Cui DM; Tang T; Chen XS; Jing XB

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C-H activation motivated by N,N'-diisopropylcarbodiimide within a lutetium complex stabilized by an amino-phosphine ligand

机译：由氨基膦配体稳定的carb络合物中N，N'-二异丙基碳二亚胺激发的C-H活化

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A lutetium bis( alkyl) complex stabilized by a flexible amino phosphine ligand LLu( CH2Si(CH3)(3))(2)(THF) (L = (2,6-C6H3( CH3)(2)) NCH( C6H5) CH2P(C6H5)(2)) was prepared which upon insertion of N, N'-diisopropylcarbodiimide led to C-H activation via metalation of the ligand aryl methyl followed by reduction of the C=N double bond.

机译：由柔性氨基膦配体LLu（CH2Si（CH3）（3））（2）（THF）（L =（2,6-C6H3（CH3）（2））NCH（C6H5）稳定的双（烷基）络合物制备了CH 2 P（C 6 H 5）（2）），其在插入N时，通过配体芳基甲基的金属化，然后还原C ＝ N双键，导致N′-二异丙基碳二亚胺导致CH活化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2007年第38期|共2248页
作者
Liu B; Yang Y; Cui DM; Tang T; Chen XS; Jing XB;
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正文语种 eng
中图分类无机化学;
关键词
EARTH-METAL COMPLEXES; OLEFIN POLYMERIZATION; ALKYL COMPLEXES; CATALYSIS; YTTRIUM; REACTIVITY; CHEMISTRY; COPOLYMERIZATION; PALLADIUM(II); ISOPRENE;

机译：大地金属络合物;烯烃聚合;烷基络合物;催化;钇;反应性;化学;共聚合;钯（II）;异戊二烯;

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1. C-H activation motivated by N,N'-diisopropylcarbodiimide within a lutetium complex stabilized by an amino-phosphine ligand [J] . Liu B, Yang Y, Cui DM, Dalton transactions: An international journal of inorganic chemistry . 2007,第38期

机译：由氨基膦配体稳定的carb络合物中N，N'-二异丙基碳二亚胺激发的C-H活化
2. Polymerization of 2,20-Dimethyltrimethylene Carbonate by Lutetium Complexes Bearing Amino-Phosphine Ligands [J] . Bo Liu, Dongmei Cui Journal of Applied Polymer Science . 2009,第5期

机译：含氨基膦配体的ute配合物聚合碳酸2,20-二甲基三亚甲基酯
3. Rare-earth metal complexes stabilized by amino-phosphine ligand. Reaction with mesityl azide and catalysis of the cycloaddition of organic azides and aromatic alkynes [J] . Liu B, Cui DM Dalton transactions: An international journal of inorganic chemistry . 2009,第3期

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4. Reactivity of a Uranium(IV) Dialkyl Complex Supported by a Rigid NON-Donor Ligand: Alkyl Exchange and C-H Activation of Pyridines [C] . Nicholas R. Andrevchuk, David J. H. Emslie Rare Earth Research Conference . 2019

机译：刚性非供体配体支持的铀（IV）二烷基复合物的反应性：烷基交换和吡啶的C-H活化
5. Mechanisms of C-H Activation by Iron Complexes Supported by Tris- and Bis(Carbene)Borate Ligands. [D] . Hickey, Anne K. 2017

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6. Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis Characterization and Catalytic Properties of the Organometallic Complexes [O] . Poulami Sengupta, Rituparna Das, Papu Dhibar, 2021

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机译：C-H键活化和异戊二烯聚合通过含有外周骨髓硼糖醇和粗水溶液（吡唑基）硼酸盐配体的烯丙基铝酸盐/亲属复合物
8. Aspects of C-H Activation in Metal Complexes Containing Sulfur Ligands [R] . 2004

机译：含硫配体的金属配合物中C-H活化的方面

C-H activation motivated by N,N'-diisopropylcarbodiimide within a lutetium complex stabilized by an amino-phosphine ligand

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