Diastereomeric separations and crystal structures of rhodium(III) and iridium(III) complexes containing adenosine and related nucleosides

Kazuaki Yamanari; Rie Ito; Shiori Yamamoto; Akira Fuyuhiro

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Diastereomeric separations and crystal structures of rhodium(III) and iridium(III) complexes containing adenosine and related nucleosides

机译：含腺苷和相关核苷的铑（III）和铱（III）配合物的非对映异构体分离和晶体结构

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Six C_3 cyclic trinuclear complexes [{M(Cp~*)(L)}_3]~(3+) (M = Rh~(III) and Ir~(III);Cp~*=n~5-C_5Me_5) containing adenosine nucleosides [L:adenosine (Hado),2'-deoxyadenosine (Hdeoado) and 5'-acetyl-2',3'-isopropylideneadenosine (Haipado)] were prepared and characterized by UV/Vis and circular dichroism (CD) spectra,NMR spectroscopy,electrospray ionization mass spectroscopy and X-ray crystal structure analysis.The isolations of one and/or two diastereomers were successfully carried out for the four systems by second-order asymmetric transformation and/or fractional crystallization.

机译：六个C_3环状三核配合物[{M（Cp〜*）（L）} _ 3]〜（3+）（M = Rh〜（III）和Ir〜（III）; Cp〜* = n〜5-C_5Me_5）制备了腺苷核苷[L：腺苷（Hado），2'-脱氧腺苷（Hdeoado）和5'-乙酰基2'，3'-异丙基亚基腺苷（Haipado）]，并通过UV / Vis和圆二色性（CD）光谱进行了表征， NMR光谱，电喷雾电离质谱和X射线晶体结构分析。通过二阶不对称转化和/或分步结晶，成功地对四个系统进行了一种和/或两种非对映异构体的分离。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第3期|共7页
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Kazuaki Yamanari; Rie Ito; Shiori Yamamoto; Akira Fuyuhiro;
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1. Diastereomeric separations and crystal structures of rhodium(III) and iridium(III) complexes containing adenosine and related nucleosides [J] . Kazuaki Yamanari, Rie Ito, Shiori Yamamoto, Dalton transactions: An international journal of inorganic chemistry . 2003,第3期

机译：含腺苷和相关核苷的铑（III）和铱（III）配合物的非对映异构体分离和晶体结构
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机译：合成具有配体（Pr2P）-P-i（C6H4-SH-2）[pr（i）PSH]（1）的中性铱（III）和铑（III）配合物; PhP（C6H4-SH-2）（2）[phPS（2）H（2）]和PhP（C2H4SH）（2）[ePS（2）H（2）]（3）。 [Ir（pr（i）PS）（3）]和[Rh（H）（phPS）的X射线晶体结构
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机译：衍生自S-（Ph2P）（2）N（CHMePh）及其铑（I），（III）和铱（III）配合物的手性硫二磷氮烷。 Ph2P（S）N（CHMePh）PPh2，{Ph2P（S）}（2）N（CHMePh）和[（Cp *）MCl {eta（2）-P，S-Ph2PNHP（S）Ph-2）的晶体结构}] BF4，Cp * = eta（5）-C5Me5;中号
4. Bifunctional Selective Hydrosilylation of Terminal Alkynes by Bis(carbene)Iridium(III)and Rhodium(III)Complexes [C] . Luis A.Oro Annual Saudi-Japan Symposium on Technology in Petroleum Refining and Petrochemicals . 2018

机译：双（卡宾烯）铱（III）和铑（III）配合物的末端炔烃的双官能选择性氢化硅烷化
5. I. Synthesis and reactivity of chiral iridium(III) and rhodium(III) complexes. II. Platinum-catalyzed iridium-methyl and iridium-phenyl bond formation [D] . Smith, Stuart Edward 2008

机译：I.手性铱（III）和铑（III）配合物的合成和反应性。二。铂催化的铱甲基和铱苯基键的形成
6. Crystal structures of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs [O] . Joseph S. Merola, Marion A. Franks 2015

机译：fac-三氯代三（三甲基膦-κP）铑（III）一水合物的晶体结构和fac-三氯代三（3-甲基膦-κP）铑（III）甲醇半溶剂化物的铑结构：与铱类似物同型的铑结构
7. Crystal structures of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs [O] . Joseph S. Merola, Marion A. Franks 2015

机译：三氯三（三甲基膦-κp）铑（III）一水合物和三氯噻吩（三甲基膦-κp）铑（III）甲醇半溶剂化物的晶体结构：与铱类似物同型的铑结构

Diastereomeric separations and crystal structures of rhodium(III) and iridium(III) complexes containing adenosine and related nucleosides

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