Nickel(II), copper(II), and cobalt(II) solid-state structures formed through hydrogen bonding with ditopic heteroscorpionate ligands

Santillan GA; Carrano CJ

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Nickel(II), copper(II), and cobalt(II) solid-state structures formed through hydrogen bonding with ditopic heteroscorpionate ligands

机译：镍（II），铜（II）和钴（II）固态结构是通过与异位异蝎子配体进行氢键形成的

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New complexes of nickel(II), copper(II), and cobalt(II) derived from bidentate coordinating heteroscorpionate ligands, (4-carboxyphenyl) bis(3,5-dimethylpyrazolyl) methane, (L4c) and (3-carboxyphenyl) bis(3,5-dimethylpyrazolyl) methane, (L3c) have been synthesized and characterized by X-ray diffraction, IR, elemental analysis and UV-vis spectroscopy. By adjusting the reaction conditions the coordination modes of the ligands can be controlled. Solid-state interactions utilizing the strong hydrogen bonding capabilities of protonated and uncoordinated carboxylate groups can be the result of these changed reaction conditions. Finally the different orientation of the carboxylate groups in the ligands L3c and L4c also affect the overall coordination modes and the nature of the solid-state interactions in these systems.

机译：镍（II），铜（II）和钴（II）的新络合物，由双齿配位的异蝎子配体，（4-羧基苯基）双（3,5-二甲基吡唑基）甲烷，（L4c）和（3-羧基苯基）双（3,5-二甲基吡唑基）甲烷（L3c）已合成，并通过X射线衍射，IR，元素分析和UV-可见光谱进行了表征。通过调节反应条件，可以控制配体的配位方式。利用质子化和未配位的羧酸酯基团强大的氢键结合能力的固态相互作用可能是这些变化的反应条件的结果。最后，配体L3c和L4c中羧酸根基团的不同取向也影响这些系统中的整体配位模式和固态相互作用的性质。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第30期|共11页
作者
Santillan GA; Carrano CJ;
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正文语种 eng
中图分类无机化学;
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METAL-ORGANIC FRAMEWORKS; PI-PI STACKING; COORDINATION CHEMISTRY; BUILDING-BLOCKS; CRYSTAL; COMPLEXES; POLYMERS; STORAGE; NETWORKS; CONSTRUCTION;

机译：金属有机框架;PI-PI叠层;配位化学;建筑砌块;晶体;复合物;聚合物;存储;网络;构造;

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1. Nickel(II), copper(II), and cobalt(II) solid-state structures formed through hydrogen bonding with ditopic heteroscorpionate ligands [J] . Santillan GA, Carrano CJ Dalton transactions: An international journal of inorganic chemistry . 2008,第30期

机译：镍（II），铜（II）和钴（II）固态结构是通过与异位异蝎子配体进行氢键形成的
2. Synthesis, structure and magnetism of a hydrogen-bond-linked three-dimensional network of a novel nickel (II)-cobalt (II)-nickel (II) complex containing a new macrocyclic mononuclear complex ligand [J] . Xiao-Zeng Li, Dai-Zheng Liao, Zong-Hui Jiang, Transition Metal Chemistry . 2003,第5期

机译：含新型大环单核配合物的新型镍（II）-钴（II）-镍（II）配合物氢键连接的三维网络的合成，结构和磁性
3. Complexes with macrocyclic ligands. IV. Heterodinuclear cobalt(II), nickel(II), copper(II), zinc(II) and palladium(II) complexes with a macrocyclic ligand of Schiff-base type: Syntheses and structures [German] [J] . Panther T., Behrens U. Zeitschrift fur Anorganische und Allgemeine Chemie . 2000,第9期

机译：与大环配体的配合物。 IV。具有席夫碱型大环配体的异核钴（II），镍（II），铜（II），锌（II）和钯（II）配合物：合成和结构[德语]
4. Gas-phase behavior of novel binuclear nickel(II) and cobalt(II) complexes with bridging phosphinato ligands under MALDI and ESI conditions [C] . Vasily Babaev, Ekaterina Trofimova, Ildar Rizvanov, International Mass Spectrometry Conference . 2014

机译：新型双核镍（II）和钴（II）复合物的气相行为，遍布MALDI和ESI条件下桥接膦酸盐配体
5. I. Tertiary aryl sulfonamides as new cross coupling partners for nickel catalyzed Kumada-Corriu-Tamao reductive and carbon-carbon bond forming cross coupling reactions. II. N-sulfonyl deprotection under mild nickel(0) catalyzed Kumada-Corriu-Tamao coupling conditions and development of the N-Ans protecting group. III. Synthesis and application of 3,3'-di-(2-pyridyl)-1,1'-bi-2-naphthol ligands [D] . Milburn, Robert Ronald 2004

机译：I.叔芳基磺酰胺作为镍催化的Kumada-Corriu-Tamao还原和碳-碳键形成交叉偶联反应的新交叉偶联伴侣。二。在温和的镍（0）下N-磺酰基脱保护催化了Kumada-Corriu-Tamao偶联条件和N-Ans保护基的发展。三， 3,3'-二-（2-吡啶基）-1,1'-bi-2-萘酚配体的合成及应用
6. Synthesis and Spectral Investigations of Manganese(II) Cobalt(II) Nickel(II) Copper(II) and Zinc(II) Complexes of New Polydentate Ligands Containing a 18-Naphthyridine Moiety [O] . Sreedasyam Jagannatha Swamy, Erra Ram Reddy, Devunuri Naga Raju, 2006

机译：新型含18-萘啶基多齿配体的锰（II）钴（II）镍（II）铜（II）和锌（II）配合物的合成和光谱研究
7. The Effects of the BF2- and B(C2H5)2-substitiition for Bridging Hydrogen Atoms in the Cobalt(II), Nickel(II), and Copper(II) Complexes with Some Oximate Ligands [O] . Yasuomi Nonaka, Kohsuke Hamada 1981

机译：BF2-和B（C2H5）2-取代用于桥接钴（II），镍（II）和铜（II）复合物中的氢原子的替代物与一些抗脂配体
8. Inorganic Coordination Polymers. Part XIX. Steric Effects of Hydrocarbon Side Groups on the Structure and Properties of Zinc(II),Cobalt(II),Manganese(II),Nickel(II) and Copper(II) Bis(Phosphinates). [R] . gillman, h. d. eichelberger, j. l. 1975

机译：无机配位聚合物。第十九部分。烃侧基的立体效应对锌（II），钴（II），锰（II），镍（II）和铜（II）双（次膦酸盐）的结构和性质的影响。

Nickel(II), copper(II), and cobalt(II) solid-state structures formed through hydrogen bonding with ditopic heteroscorpionate ligands

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