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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Assembly of unusual Zn-cluster compounds based on pyridinealcohol platforms
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Assembly of unusual Zn-cluster compounds based on pyridinealcohol platforms

机译:基于吡啶醇平台的非常规锌簇化合物的组装

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摘要

The assembly formation of Zn cluster compounds comprising pyridinealcohol ligands is described and their solution and solid state features have been determined using NMR spectroscopy and X-ray diffraction. The di-Zn complex 5 and tetra-Zn complex 7 may serve as accessible structural models for the active site of various multinuclear Zn-containing metalloenzymes. Their phosphoester cleavage activity was tested and correlated with their dynamic structural features.
机译:描述了包含吡啶醇配体的Zn簇化合物的组装形式,并使用NMR光谱和X射线衍射确定了它们的溶液和固态特征。二锌配合物5和四锌配合物7可以用作各种含多核含锌金属酶的活性位点的可及结构模型。测试了它们的磷酸酯裂解活性,并将其与动态结构特征相关联。

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