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Facile synthesis and characterization of novel coronene chromophores and their application to LCD color filters

机译:新型co烯发色团的简便合成与表征及其在LCD彩色滤光片中的应用

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摘要

New coronene derivatives, diphenylcoronene tetracarboxdiimide and monophenylbenzoperylene tetra-carboxdiimide, were synthesized from N,N'-bis(2.6-diisopropylphenyl)-1,7-dibromoperylene-3,4,9,10-tetracarboxdiimide via a one-step reaction. The suggested synthetic route is the simplest and most economical among the methods to extend the aromatic systems along the short molecular axis of perylene. The synthesized molecules exhibited superior stability and color strength as yellow chromophores. They were characterized by significant hypsochromic shifts of the absorption compared to perylene tetracarboxdiimide and high fluorescence quantum yields.
机译:通过一步反应,由N,N'-双(2.6-二异丙基苯基)-1,7-二溴,-3,4,9,10-四羧二酰亚胺合成了新的二苯并呋喃衍生物四苯基二酰亚胺和单苯基苯并co四丁基。在沿per的短分子轴扩展芳族体系的方法中,建议的合成路线是最简单,最经济的方法。合成的分子显示出优异的稳定性和色强度,为黄色生色团。与per四碳二亚胺相比,它们的特征在于吸收的显着变色移动和高荧光量子产率。

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