Metal Chelations in asymmetric diels-alder reaction

Kyoo-Hyun Chung; Chan-Kook Chu; Min-Ho Chang

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Metal Chelations in asymmetric diels-alder reaction

机译：不对称狄尔斯－阿尔德反应中的金属螯合

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In the presence of chiral catalysts,Diels-Alder reaction of a N-acryloyl chiral dienophiole with cyclopentadiene gave the corresponding endo norbornenecarboxamide with high diastereoselectivity.In the reaction,8-membered chelation was effective enough to distinguish transoid and cisoid conformation in the presence of divalent Lewis acid catalysts,such as TiCl_4.

机译：在手性催化剂的存在下，N-丙烯酰基手性二酚与环戊二烯的Diels-Alder反应得到相应的内降冰片烯羧酰胺，具有非对映选择性。二价路易斯酸催化剂，例如TiCl_4。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2003年第9期|共5页
作者
Kyoo-Hyun Chung; Chan-Kook Chu; Min-Ho Chang;
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正文语种 eng
中图分类杂环化合物;
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1. Metal Chelation in Asymmetric Diels-Alder Reaction(II) [J] . Kyoo-Hyun Chung, Chan-Kook Chu, Min-Ho Chang Bulletin of the Korean Chemical Society . 2004,第3期

机译：不对称Diels-Alder反应中的金属螯合（II）
2. Metal Chelations in asymmetric diels-alder reaction [J] . Kyoo-Hyun Chung, Chan-Kook Chu, Min-Ho Chang Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2003,第9期

机译：不对称狄尔斯－阿尔德反应中的金属螯合
3. Asymmetric synthesis of a chiral arsinophosphine via a metal template promoted asymmetric Diels-Alder reaction between diphenylvinylphosphine and 2-furyldiphenylarsine [J] . Tan KW, Liu FL, Li YX, Journal of Organometallic Chemistry . 2006,第22期

机译：通过金属模板的不对称合成手性砷化膦促进了二苯基乙烯基膦和2-呋喃二苯基phenyl之间的不对称Diels-Alder反应
4. β-Amino alcohol organocatalyst for asymmetric hetero Diels-Alder reaction of isatins and enones [C] . Perumalsamy Parasuraman, Chigusa Seki, Koji Uwai 日本化学会春季年会講演予稿集 . 2018

机译：β-氨基醇有机催化剂对异素和蜗杆的不对称杂生Diels- ald反应
5. Chelation control in carbonyl reductions and TADDOL catalyzed Diels-Alder reactions. [D] . Collibee, Scott E. 1997

机译：羰基还原中的螯合控制和TADDOL催化的Diels-Alder反应。
6. Chiral GAP catalysts of phosphonylated imidazolidinones and their applications in asymmetrical Diels-Alder and Friedel-Craft reactions [O] . Shuo Qiao, Junming Mo, Cody B. Wilcox, -1

机译：膦酰化咪唑烷酮的手性GAP催化剂及其在不对称Diels-Alder和Friedel-Craft反应中的应用
7. Diastereoselective Diels-Alder Reactions of N-Sulfonyl-1-aza-1, 3-butadienes with Optically Active Enol Ethers: An Asymmetric Variant of the 1-Azadiene Diels-Alder Reaction [O] . -1

机译：具有光学活性烯醇醚的N-磺酰基-1-α-1,3-丁二烯的非对映选择性Diels-Alder反应：1-氮二烯Diels-桤木反应的不对称变体

Metal Chelations in asymmetric diels-alder reaction

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