STEREOSELECTIVE SYNTHESIS OF THE GHI-RING OF MAITOTOXIN,A MARINE POLYCYCLIC ETHER

Masanori Satoh; Masaki Mori; Tadashi Nakata

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STEREOSELECTIVE SYNTHESIS OF THE GHI-RING OF MAITOTOXIN,A MARINE POLYCYCLIC ETHER

机译：海洋多环胺类毒素毒素的立体选择性合成

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The GHI-ring of maitotoxin,a marine polycyclic ether,was stereoselectively synthesized by way of SmI2-induced reductive cyclization of beta-alkoxyacrylate and aldehyde.Maitotoxin (1),isolated from the dinoflagellate Gambierdiscus toxicus,is the most toxic and largest natural product (MW 3422) so far known,except for biopolymers such as proteins or polysaccharides.

机译：通过SmI2诱导的β-烷氧基丙烯酸酯和醛的还原环化反应，立体选择性地合成了海洋毒素多环醚的GHI环。从鞭毛鞭毛鞭毛藻中分离出的毒素（1）是毒性最大，天然最大的产物。（MW 3422）到目前为止，除了蛋白质或多糖等生物聚合物外。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2007年第0期|共5页
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Masanori Satoh; Masaki Mori; Tadashi Nakata;
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1. STEREOSELECTIVE SYNTHESIS OF THE GHI-RING OF MAITOTOXIN,A MARINE POLYCYCLIC ETHER [J] . Masanori Satoh, Masaki Mori, Tadashi Nakata Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007,第0期

机译：海洋多环胺类毒素毒素的立体选择性合成
2. Synthesis of Sub-units of Marine Polycyclic Ethers by Ring-closing Metathesis and Hydroboration of Enol Ethers [J] . J. Stephen Clark, Jason G. Kettle Tetrahedron . 1999,第27期

机译：闭环易位和烯醇醚的硼氢化反应合成海洋多环醚的亚基
3. Nature Inspired Molecular Design: Stereoselective Synthesis of Bicyclic and Polycyclic Ethers for Potent HIV-1 Protease Inhibitors [J] . Ghosh Arun K., Brindisi Margherita Asian Journal of Organic Chemistry . 2018,第8期

机译：自然启发分子设计：效率HIV-1蛋白酶抑制剂的双环和多环醚的立体选择性合成
4. Stereoselective synthesis of exocyclig enol ethers: Synthesis of substituted spiroketals [C] . Benjamin Bourdon, David Gueyrard, Peter Goekjian European Symposium on Organic Chemistry . 2009

机译：Exocyclig Enol ethers的立体选择性合成：取代螺旋藻的合成
5. I. Stereoselective Construction of Polycyclic Architectures: Enantioselective Catalytic Transannular Ketone-Ene Reactions and an Enantioselective Total Synthesis of (+)-Reserpine II. Synthesis of Chiral Bisthioureas for Anion-Abstraction Catalysis. [D] . Rajapaksa, Naomi Samadara. 2013

机译：I.多环结构的立体选择性构建：对映选择性催化环戊酮-烯反应和（+）-利血平的对映选择性总合成II。用于阴离子提取催化的手性双硫脲的合成。
6. Nature Inspired Molecular Design: Stereoselective Synthesis of Bicyclic and Polycyclic Ethers for Potent HIV-1 Protease Inhibitors [O] . Arun K. Ghosh, Margherita Brindisi -1

机译：受自然启发的分子设计：用于有效的HIV-1蛋白酶抑制剂的双环和多环醚的立体选择性合成。
7. A Convergent Coupling Strategy for the Formation of Polycyclic Ethers: Stereoselective Synthesis of the BCDE Fragment of Brevetoxin A [O] . -1

机译：形成多环醚的收敛耦合策略：Brevetoxin A的BCDE片段的立体选择性合成
8. Rapid Stereoselective Synthesis of Fluorinated Carbohydrates. Addition of Acetyl Hypofluorite to Vinyl Ether Derivatives of Sugars [R] . Adam, M. J., Neeser, J. R., Hall, L. D., 1983

机译：氟化碳水化合物的快速立体选择性合成。在乙烯基醚衍生物中添加乙酰基次氟酸盐

STEREOSELECTIVE SYNTHESIS OF THE GHI-RING OF MAITOTOXIN,A MARINE POLYCYCLIC ETHER

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