QUASSINOID SUPPORT STUDIES:INCREASING STEREOCONTROL IN A PERHYDRONAPHTHALENE SYNTHESIS BY RESTRICTING CONFORMATIONAL DEGREES OF FREEDOM

David J.Hart; Dexi Yang

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >QUASSINOID SUPPORT STUDIES:INCREASING STEREOCONTROL IN A PERHYDRONAPHTHALENE SYNTHESIS BY RESTRICTING CONFORMATIONAL DEGREES OF FREEDOM

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QUASSINOID SUPPORT STUDIES:INCREASING STEREOCONTROL IN A PERHYDRONAPHTHALENE SYNTHESIS BY RESTRICTING CONFORMATIONAL DEGREES OF FREEDOM

机译：类肌醇的支持研究：通过限制构象自由度来增强邻苯二甲萘合成中的立体控制

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Free radical cyclization of 15 provides trans-perhydronaphthalene (16) in high yield and with much better stereoselectivity than conformationally less constrained analogs.The quassinoids are a large family of terpenoid natural products exemplified by chaparrinone (l).1 The quassinoids have been of long-standing interest to the medicinal chemistry community because of their broad biological activities.

机译：15的自由基环化可提供高收率的反式全氢萘（16），其立体选择性比构象上受限制较少的类似物更好。拟南芥类是萜类天然产物的一大家族，例如查帕瑞酮（l）。1拟南芥很长由于其广泛的生物活性而对药物化学界具有浓厚的兴趣。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2007年第1期|共5页
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David J.Hart; Dexi Yang;
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1. QUASSINOID SUPPORT STUDIES:INCREASING STEREOCONTROL IN A PERHYDRONAPHTHALENE SYNTHESIS BY RESTRICTING CONFORMATIONAL DEGREES OF FREEDOM [J] . David J.Hart, Dexi Yang Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007,第1期

机译：类肌醇的支持研究：通过限制构象自由度来增强邻苯二甲萘合成中的立体控制
2. Conformational effects and stereocontrol in synthesis studies of medium-ring dolabellane carbocycles [J] . Williams David R., Robinson Leslie A., Bawel Seth A. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第23期

机译：构型效应和立体控制在中环dolabellane碳环化合物的合成研究中
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5. eta6-Arenechromium tricarbonyl complexes: Conformational analysis, stereocontrol in nucleophilic addition and applications in organic synthesis. [D] . Paramahamsan, Harinandini. 2005

机译：eta6-芳烃铬三羰基配合物：构象分析，亲核加成中的立体控制和在有机合成中的应用。
6. Conformational effects and stereocontrol in synthesis studies ofmedium-ring dolabellane carbocycles [O] . David R. Williams, Leslie A. Robinson, Seth A. Bawel -1

机译：构象效应和立体控制中环多菌灵碳环化合物
7. A Study Concerning Passage through Resonances of a Rotor Supported by Many Degrees of Freedom Vibration Isolation System [O] . Katsumasa MATSUURA 1982

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QUASSINOID SUPPORT STUDIES:INCREASING STEREOCONTROL IN A PERHYDRONAPHTHALENE SYNTHESIS BY RESTRICTING CONFORMATIONAL DEGREES OF FREEDOM

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