SKELETAL DIVERSITY BY UGI FOUR-COMPONENT COUPLING REACTION AND POST-UGI REACTIONS

Masato Oikawa; Shinya Naito; Makoto Sasaki

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SKELETAL DIVERSITY BY UGI FOUR-COMPONENT COUPLING REACTION AND POST-UGI REACTIONS

机译：UGI四元偶联反应和后UGI反应引起的骨骼多样性

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Here we report a strategy to alter the skeletal complexity of Ugi four-component coupling reaction products by using allylations followed by ring-closing metathesis.Principal component analysis is also performed for these compounds.Molecular diversity is highly important for the de novo development of biologically functional small molecules for use in chemical genetics (or chemical biology),a research area of chemistry-driven biology.

机译：本文报道了一种通过烯丙基化和闭环复分解改变Ugi四组分偶联反应产物骨架复杂性的策略，对这些化合物也进行了主成分分析，分子多样性对于生物学从头发展至关重要用于化学遗传学（或化学生物学）的功能性小分子，化学驱动生物学的一个研究领域。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2007年第1期|共16页
作者
Masato Oikawa; Shinya Naito; Makoto Sasaki;
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1. SKELETAL DIVERSITY BY UGI FOUR-COMPONENT COUPLING REACTION AND POST-UGI REACTIONS [J] . Masato Oikawa, Shinya Naito, Makoto Sasaki Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2007,第1期

机译：UGI四元偶联反应和后UGI反应引起的骨骼多样性
2. Ammonia in Ugi reactions - Four-component versus six-component couplings [J] . Pick R, Bauer M, Kazmaier U, Synlett . 2005,第5期

机译：Ugi反应中的氨-四组分与六组分偶联
3. One-pot synthesis of quinoline-fused [1,4]thiazepines via the tandem Ugi/post-Ugi reactions [J] . Ghandi Mehdi, Efteghar Irene, Abbasi Alireza Journal of the Iranian Chemical Society . 2019,第2期

机译：通过串联UGI /后UGI反应的单壶合成喹啉融合[1,4]噻嗪类化合物
4. An improved approach to the synthesis of N-acyl-alpha,alpha-dialkylglycines,their esters and amides using Ugi's four-component reaction [C] . Susana P.G.Costa, Hernani L.S.Maia, Silvia M.A.Pereira-Lima European Peptide Symposium . 2002

机译：使用UGI的四分组分反应合成N-酰基-α，α-二烷基甘氨酸，酯和酰胺的改进方法
5. I. Microwave-influenced diversity-oriented synthesis of biologically relevant small and natural-product-like molecules via multicomponent coupling reactions. II. Synthetic studies toward the total synthesis of the repeating tetrasaccharide unit of zwitterionic polysaccharide PS A1. [D] . Santra, Soumava. 2010

机译：I.通过多组分偶联反应，微波影响生物相关的小分子和天然产物样分子的面向多样性的合成。二。对两性离子多糖PS A1的重复四糖单元进行全合成的合成研究。
6. Expanding the substrate scope of ugi five-center four-component reaction U-5C-4CR): ketones as coupling partners for secondary amino acids [O] . Maciej Dawidowski, Sławomir Sobczak, Marcin Wilczek, -1

机译：扩大ugi五中心四组分反应U-5C-4CR）的底物范围：酮作为仲氨基酸的偶联伙伴
7. Expanding the substrate scope of ugi five-center, four-component reaction U-5C-4CR): ketones as coupling partners for secondary amino acids [O] . Maciej Dawidowski, Sławomir Sobczak, Marcin Wilczek, 2013

机译：扩大ugi五中心四组分反应U-5C-4CR）的底物范围：酮作为仲氨基酸的偶联伙伴
8. Phase Transfer Pd(O) Catalyzed Polymerization Reactions. 1. Synthesis of 1,2-(4,4'-Dialkoxyaryl)Acetylene Monomers and 1,4-Bis(2-(4',4''-Dialkoxyphenyl)Ethynyl)Benzene Derivatives by Phase Transfer Pd(O)/Cu(I) Catalyzed Coupling Reactions. [R] . Pugh, C., Percec, V. 1990

机译：相转移pd（O）催化的聚合反应。 1.相转移pd（O）/ Cu合成1,2-（4,4'-二烷氧基芳基）乙炔单体和1,4-双（2-（4'，4'-二烷氧基苯基）乙炔基）苯衍生物（I）催化的偶联反应。

SKELETAL DIVERSITY BY UGI FOUR-COMPONENT COUPLING REACTION AND POST-UGI REACTIONS

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