STEREOSELECTIVE SYNTHESIS OF gamma-AND delta-SULTAMS BY INTRAMOLECULAR DIELS-ALDER REACTION OF VINYLSULFONAMIDES POSSESSING AN ACYCLIC OR CARBOCYCLIC 1,3-DIENE MOIETY

Victor O.Rogachev; Victor D.Filimonov; Roland Frohlich; Olga Kataeva; Peter Metz

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STEREOSELECTIVE SYNTHESIS OF gamma-AND delta-SULTAMS BY INTRAMOLECULAR DIELS-ALDER REACTION OF VINYLSULFONAMIDES POSSESSING AN ACYCLIC OR CARBOCYCLIC 1,3-DIENE MOIETY

机译：乙烯基硫代酰胺类化合物具有环状或羧基的1,3-二烯部分的分子间狄尔斯-阿尔德反应的立体选择性合成γ-和-δ-硫

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A range of novel gamma-and enantiopure delta-sultams was prepared by intramolecular [4+2] cycloaddition of vinylsulfonamides with purely thermal activation and under high pressure.Sultams are useful heterocycles for asymmetric synthesis and medicinal chemistry.Recently developed powerful methodologies for the generation of these cyclic sulfonamides include the intramolecular Diels-Alder reaction,sulfonamide dianion alkylation,radical cyclization,ring closing metathesis,and intramolecular Heck cyclization.

机译：分子内乙烯基磺酰胺的分子内[4 + 2]环加成并具有纯热活化和高压作用，制得了一系列新型的γ-和对映体-δ-异阿马酸。Sultams是有用的杂环，可用于不对称合成和药物化学。这些环状磺酰胺包括分子内Diels-Alder反应，磺酰胺二阴离子烷基化，自由基环化，闭环复分解和分子内Heck环化。

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《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2006年第2期|共7页
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Victor O.Rogachev; Victor D.Filimonov; Roland Frohlich; Olga Kataeva; Peter Metz;
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1. STEREOSELECTIVE SYNTHESIS OF gamma-AND delta-SULTAMS BY INTRAMOLECULAR DIELS-ALDER REACTION OF VINYLSULFONAMIDES POSSESSING AN ACYCLIC OR CARBOCYCLIC 1,3-DIENE MOIETY [J] . Victor O.Rogachev, Victor D.Filimonov, Roland Frohlich, Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2006,第2期

机译：乙烯基硫代酰胺类化合物具有环状或羧基的1,3-二烯部分的分子间狄尔斯-阿尔德反应的立体选择性合成γ-和-δ-硫
2. Lewis Acid Catalyzed Intramolecular Diels-Alder Reactions of Acyclic (Z)-Substituted 1,3-Dienes [J] . Neal A.Yakelis, William R.Roush Organic letters . 2001,第6期

机译：路易斯酸催化无环（Z）取代的1，3-二烯的分子内Diels-Alder反应
3. Novel Synthesis of Dienylsiloxanes Stereoselective Synthesis of 3-Cyclohexene-l,2-diols by Intramolecular Diels-Alder Reactions of Siloxane-Tethered Bis-Dienes [J] . Ruey-Min Chen, Wu-Wang Weng, Tien-Yau Luh The Journal of Organic Chemistry . 1995,第11期

机译：新型的二烯基硅氧烷的合成通过硅氧烷连接的双二烯的分子内Diels-Alder反应立体选择性地合成3-环己烯-1,2-二醇
4. Stereoselective Synthesis of Dihydropyrans by Hetero Diels-Alder Reactions [C] . Franco Cozzi, Valentina Molteni Seminars in organic synthesis : XXII summer school "A. Corbella" . 1997

机译：杂Diels-Alder反应立体选择性合成二氢吡喃
5. Intramolecular Diels-Alder reactions of (Z)-substituted-1,3-dienes and studies directed toward the total synthesis of superstolide A. [D] . Yakelis, Neal A. 2003

机译：（Z）-取代的1,3-二烯类的分子内Diels-Alder反应及研究涉及超杀菌素A的全合成。
6. Type 2 Intramolecular N-acylazo Diels-Alder Reaction: Regio- and Stereoselective Synthesis of Bridgehead Bicyclic 12-Diazines [O] . Claudia L. Molina, Chun P. Chow, Kenneth J. Shea -1

机译：2型分子内N-酰基Diels-Alder反应：桥头双环12-二嗪的区域和立体选择性合成
7. Stereoselective Synthesis of Decalines via Tandem Photooxidation - Intramolecular Diels-Alder Reactions of Bis-Furans [O] . Gelling O.J., Meesters L., Feringa Bernard 1990

机译：通过串联光氧化立体选择性合成癸胺-双呋喃的分子内Diels-Alder反应
8. Diels-Alder Reactions of a Surfactant 1,3-Diene [R] . Jaeger, D. A., Shinozaki, H., Goodson, P. A. 1991

机译：表面活性剂1,3-二烯的Diels-alder反应

STEREOSELECTIVE SYNTHESIS OF gamma-AND delta-SULTAMS BY INTRAMOLECULAR DIELS-ALDER REACTION OF VINYLSULFONAMIDES POSSESSING AN ACYCLIC OR CARBOCYCLIC 1,3-DIENE MOIETY

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