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首页> 外文期刊>Journal of Applied Polymer Science >Novel routes to polyelectrolytes and reactive polymers via ROMP
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Novel routes to polyelectrolytes and reactive polymers via ROMP

机译：通过ROMP通往聚电解质和反应性聚合物的新途径

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摘要

Various derivatives of norbornene and 7-oxanorbornenedicarboxylic acid have been synthesized and polymerized via Ring Opening Metathesis Polymerization (ROMP). The introduction of tetrahydropyranyl moieties as protection groups opened a way for the synthesis of polyelectrolytes through well-defined transition metal alkylidene catalysts that are usually deactivated by reactions with acidic protons. The incorporation of methacrylate groups in the polycarboxylic acids was achieved either by copolymerization of methacrylate functionalized norbornene or 7-oxanorbornene derivatives, or by the polymer analogous reaction of the polycarboxylic acids with glycidyl methacrylate (GMA). These materials are soluble in water as well as in ethanol and undergo cross-linking reactions initiated by UV light. (C) 2000 John Wiley & Sons, Inc. [References: 29]
机译：已经通过开环复分解聚合（ROMP）合成并聚合了降冰片烯和7-氧杂降冰片烯二羧酸的各种衍生物。引入四氢吡喃基部分作为保护基团为通过明确定义的过渡金属亚烷基催化剂合成聚电解质开辟了途径，所述过渡金属亚烷基催化剂通常通过与酸性质子反应而失活。通过使甲基丙烯酸酯官能化的降冰片烯或7-氧杂降冰片烯衍生物共聚，或通过使多元羧酸与甲基丙烯酸缩水甘油酯的聚合物类似反应，来实现将甲基丙烯酸酯基团引入多元羧酸。这些材料可溶于水以及乙醇，并经历紫外线引发的交联反应。 （C）2000 John Wiley＆Sons，Inc. [参考：29]

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