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Melamine Salts as Hardeners for Urea Formaldehyde Resins

机译:三聚氰胺盐作为尿素甲醛树脂的固化剂

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Various salts derived from melamine and organic acids were prepared and used as melamine substitutes for melamine urea formaldehyde (MUF) resins. The synthesis of these melamine salts and a detailed characterization of their stoichiometry are described. All salts form 1:1 or 1:2 stoichiometries in a homogeneous reaction. They crystallize during cooling of the hot and diluted reaction mixture. Both ~(13)C-NMR and ~(15)N-NMR data are reported and point toward the formation of real ionic structures. Most salts have higher water solubility than that of pure melamine and are tested for their ability to substitute melamine in MUF resins. The mechanical and chemical properties of plywood panels made up of traditional MUF resins and mixtures of UF resins with melamine salts are investigated.
机译:制备了源自三聚氰胺和有机酸的各种盐,并将其用作三聚氰胺脲甲醛(MUF)树脂的三聚氰胺替代品。描述了这些三聚氰胺盐的合成及其化学计量的详细表征。所有盐在均相反应中形成1:1或1:2的化学计量。它们在热的和稀释的反应混合物冷却期间结晶。 〜(13)C-NMR和〜(15)N-NMR数据均已报道,并指向真实离子结构的形成。大多数盐具有比纯三聚氰胺更高的水溶性,并测试了它们在MUF树脂中替代三聚氰胺的能力。研究了由传统的MUF树脂和UF树脂与三聚氰胺盐的混合物组成的胶合板的机械和化学性能。

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