A Novel Highly Copper(II)-Selective Chelating Ion Exchanger Based on Poly(Glycidyl Methacrylate-co-Ethylene Dimethacrylate) Beads Modified with Aspartic Acid Derivative

Daniel Horak; Milan J.Benes; Klara Gumargalieva; Guennadi Zaikov

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A Novel Highly Copper(II)-Selective Chelating Ion Exchanger Based on Poly(Glycidyl Methacrylate-co-Ethylene Dimethacrylate) Beads Modified with Aspartic Acid Derivative

机译：基于天冬氨酸衍生物改性的聚甲基丙烯酸缩水甘油酯-二甲基丙烯酸乙二酯共聚物微珠的新型高铜（II）选择性螯合离子交换剂

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Anchoring the hydroxyaspartic acid onto poly(glycidyl methacrylate-co-ethylene dimethacrylate) (poly(GMA-co-EDMA)) beads or eoxysuccinic acid onto ammonium-modified poly(GMA-co-EDMA) beads resulted in a novel chelating resin, which contained up to 0.37 mmol of the ligand per gram of resin. Batch extraction experiments showed a very hgih selectivity for Cu~(2+) over Zn~(2+) and Cd~(2+) ions in buffered solutions under competitive conditions.

机译：将羟基天冬氨酸锚定在聚甲基丙烯酸缩水甘油酯-共聚二甲基丙烯酸乙二酯乙烯共聚物（聚（GMA-co-EDMA））珠上或将环氧丁二酸固定在铵改性的聚（GMA-co-EDMA）珠上，形成一种新型的螯合树脂，每克树脂最多包含0.37 mmol的配体。批量萃取实验表明，在竞争条件下，缓冲溶液中Cu〜（2+）对Zn〜（2+）和Cd〜（2+）离子的选择性非常高。

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《Journal of Applied Polymer Science》 |2001年第7期|共4页
作者
Daniel Horak; Milan J.Benes; Klara Gumargalieva; Guennadi Zaikov;
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正文语种 eng
中图分类高分子化学（高聚物）;高分子化合物产品;有机化学;
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1. Novel highly copper(II)-selective chelating ion exchanger based on poly(glycidyl methacrylate-co-ethylene dimethacrylate) beads modified with aspartic acid derivative [J] . D. Horak, M. Benes, K. Gumargalieva Oxidation Communications . 2002,第2期

机译：基于天冬氨酸衍生物改性的聚甲基丙烯酸缩水甘油酯-二甲基丙烯酸乙二酯共聚物微珠的新型高铜（II）选择性螯合离子交换剂
2. A Novel Highly Copper(II)-Selective Chelating Ion Exchanger Based on Poly(Glycidyl Methacrylate-co-Ethylene Dimethacrylate) Beads Modified with Aspartic Acid Derivative [J] . Daniel Horak, Milan J.Benes, Klara Gumargalieva, Journal of Applied Polymer Science . 2001,第7期

机译：基于天冬氨酸衍生物改性的聚甲基丙烯酸缩水甘油酯-二甲基丙烯酸乙二酯共聚物微珠的新型高铜（II）选择性螯合离子交换剂
3. A Novel Highly Copper(II)-selective Chelating lon Exchanger Based on Poly(Glycidyl Methacrylate-co-ethylene Dimethacrylate) Beads Modified with Aspartic Acid Derivative [J] . Daniel Horak, Milanbenes, Klara Gumargalieva, International Journal of Polymeric Materials . 2001,第1期

机译：基于天冬氨酸衍生物改性的聚甲基丙烯酸缩水甘油酯-共聚二甲基丙烯酸乙二酯的新型高铜（II）选择性螯合离子交换剂
4. GYPSUM SCALE FORMATION ON HEAT EXCHANGER SURFACES: THE INFLUENCE OF POLY(ACRYLIC ACID), POLY(ASPARTIC ACID), AND POLY(GLUTAMIC ACID) [C] . Zahid AMJAD Acta polytechnica scandinavica . 1997

机译：换热表面上的石膏鳞片形成：聚（丙烯酸），聚（ASPADIC酸）和聚（谷氨酸）的影响
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机译：聚（甲基丙烯酸缩水甘油酯 - 共聚乙二醇二甲基丙烯酸酯）与酸改性膨润土功能化大孔纳米复合材料吸附不同酚衍生物

A Novel Highly Copper(II)-Selective Chelating Ion Exchanger Based on Poly(Glycidyl Methacrylate-co-Ethylene Dimethacrylate) Beads Modified with Aspartic Acid Derivative

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