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首页> 外文期刊>Journal of Applied Polymer Science >PHOSPHORUS-CONTAINING EPOXY FOR FLAME RETARDANT .1. SYNTHESIS, THERMAL, AND FLAME-RETARDANT PROPERTIES
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PHOSPHORUS-CONTAINING EPOXY FOR FLAME RETARDANT .1. SYNTHESIS, THERMAL, AND FLAME-RETARDANT PROPERTIES

机译：阻燃剂含磷环氧树脂.1。合成，热和阻燃性能

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摘要

A new phosphorus-containing oxirane, bis-(3-glycidyloxy) phenylphosphine oxide (BGPPO), was synthesized. Further curing BGPPO with diamine curing agents, dicyanodiamide (DICY), 4,4'-diaminodiphenylmethane (DDM), and 4,4'-diaminodiphenylsulfone (DDS), respectively, resulted in several phosphorylated epoxy resins. Compared with Epon 828, Eponex 1015, and DER 732, BGPPO showed relatively high reactivity toward diamine agents via DSC studies. Furthermore, the reactivity of the three curing agents toward BGPPO were found to be in the order of DDM > DICY > DDS. Thermal stability and the weight loss behavior of the cured polymers were studied by TGA. The phosphorylated resins showed lower weight loss temperatures and higher char yields than did the Epon 828-based resins. The high char yields as well as high limited oxygen index (LOI) values of the BGPPO-based resins confirmed the effectiveness of phosphorus-containing epoxy resins as flame retardants. (C) 1996 John Wiley & Sons, Inc. [References: 17]
机译：合成了一种新的含磷环氧乙烷双（3-缩水甘油基氧基）苯基氧化膦（BGPPO）。分别用二胺固化剂，二氰基二酰胺（DICY），4,4'-二氨基二苯甲烷（DDM）和4,4'-二氨基二苯砜（DDS）进一步固化BGPPO，得到了几种磷酸化环氧树脂。与Epon 828，Eponex 1015和DER 732相比，BGPPO通过DSC研究显示对二胺类试剂的反应性较高。此外，发现这三种固化剂对BGPPO的反应性依次为DDM> DICY> DDS。通过TGA研究了固化聚合物的热稳定性和失重行为。与基于Epon 828的树脂相比，磷酸化的树脂显示出更低的失重温度和更高的炭收率。 BGPPO基树脂的高炭收率和高极限氧指数（LOI）值证实了含磷环氧树脂作为阻燃剂的有效性。 （C）1996 John Wiley＆Sons，Inc. [参考：17]

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