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New polymer bipolar plates for polymer electrolyte membrane fuel cells: Synthesis and characterization

机译:用于聚合物电解质膜燃料电池的新型聚合物双极板:合成与表征

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摘要

Carbon black (CB) and polyvinylidene fluoride (PVDF) composites were obtained and subsequently characterized, both microstructurally (DSC and DMA) and electrically. In addition, the electrochemical performance of these materials was tested in the form of bipolar plates, expressly manufactured for this purpose and incorporated in a conventional fuel cell. The results obtained allow for the conclusion that CB incorporation into PVDF yields polymer composite materials with electrical conductivity of about 2.4 S/cm, which may be thermically processed and given any convenient shape with the means conventionally applied in the field of polymer technologies. It was found that CB concentration slightly affects the microstructural parameters of the composites (melting temperature, glass-transition temperature, Avrami kinetic parameters, etc.). (C) 2002 John Wiley Sons, Inc. [References: 12]
机译:获得了炭黑(CB)和聚偏二氟乙烯(PVDF)复合材料,随后对其进行了微观结构(DSC和DMA)和电学表征。另外,以双极板的形式测试了这些材料的电化学性能,该双极板是专门为此目的制造的,并结合在常规燃料电池中。所获得的结果可以得出这样的结论,即将CB掺入PVDF中可以得到导电率约为2.4 S / cm的聚合物复合材料,可以对其进行热加工并采用常规应用于聚合物技术领域的方法制成任何方便的形状。发现CB浓度对复合材料的微结构参数(熔融温度,玻璃化转变温度,Avrami动力学参数等)有轻微影响。 (C)2002 John Wiley Sons,Inc. [参考:12]

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