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首页> 外文期刊>Journal of Applied Polymer Science >STUDIES ON POLY(2-HYDROXY-4-ACRYLOYLOXYBENZOPHENONE) METAL COMPLEXES
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STUDIES ON POLY(2-HYDROXY-4-ACRYLOYLOXYBENZOPHENONE) METAL COMPLEXES

机译：聚（2-羟基-4-乙酰氧基苯甲酮）金属配合物的研究

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摘要

2-Hydroxy-4-acryloyloxybenzophenone (HABP), prepared from acryloyl chloride with 2,4- dihydroxybenzophenone, was polymerized in methyl ethyl ketone at 70 degrees C using benzoyl peroxide as initiator. Polychelates were obtained in the dimethylformamide solution of poly(HABP) containing a few drops of ammonia with the aqueous solution of Cu(II)/Ni(II) ions. The polymer and polychelates were characterized by elemental analyses and spectral studies. Elemental analyses of the polychelates suggest a metal to ligand ratio of 1:2. The IR spectral data of polychelates indicate that the metals were coordinated through the oxygen of the keto group and the oxygen of the phenolic-OH group. The diffuse reflectance spectra, electron paramagnetic resonance, and magnetic moments of the polychelates show an octahedral and square planar structure for poly(HABP)-Ni(II) and poly(HABP)-Cu(II) complexes, respectively. X-ray diffraction studies revealed a high crystalline nature of the polychelates. The thermal properties of polymer and metal complexes and their catalytic activity are discussed. (C) 1996 John Wiley & Sons, Inc. [References: 28]
机译：由丙烯酰氯与2，4-二羟基二苯甲酮制得的2-羟基-4-丙烯酰氧基二苯甲酮（HABP）在70℃下使用过氧化苯甲酰作为引发剂在甲基乙基酮中聚合。在含有几滴氨水的聚（HABP）的二甲基甲酰胺溶液中，与Cu（II）/ Ni（II）离子水溶液一起获得了多螯合物。通过元素分析和光谱研究表征了聚合物和多螯合物。聚螯合物的元素分析表明金属与配体的比例为1：2。聚螯合物的IR光谱数据表明，金属通过酮基的氧和酚-OH基的氧配位。聚螯合物的漫反射光谱，电子顺磁共振和磁矩分别显示了聚（HABP）-Ni（II）和聚（HABP）-Cu（II）配合物的八面体和正方形平面结构。 X射线衍射研究表明聚螯合物具有高结晶性。讨论了聚合物和金属配合物的热性质及其催化活性。 （C）1996 John Wiley＆Sons，Inc. [参考：28]

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