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Preparation, characterization, and some physical properties of polypropylene/poly(methyl acrylate)-grafted glass wool composites

机译:聚丙烯/聚丙烯酸甲酯接枝玻璃棉复合材料的制备,表征及一些物理性能

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Polypropylene/poly(methyl acrylate)-grafted glass wool (PMA-g-GW) mixes were prepared. The polymerization process was carried out using potassium persulfate (PPS) and PPS/acetone sodium bisulfite (ASBS) as a redox-pair initiation system at 60 and 70degreesC. The effect of using PPS or PPS/ASBS on the grafting percent and conversion percent reveals that the conversion percent values on using PPS as an initiator are higher than those of PPS/ASBS, while in the case of grafting, the inverse is true, that is, using PPS as an initiator gives grafting percent values lower than those that can be obtained using PPS/ASBS. The dielectric properties, thermal diffusivity, specific heat capacity, and thermal conductivity of PP loaded with modified glass wool as a function of different types and concentrations of initiators-used in the grafting polymerization process, namely, PPS and the redox initiating system-were also studied. (C) 2002 Wiley Periodicals, Inc. [References: 21]
机译:制备了聚丙烯/聚(丙烯酸甲酯)接枝的玻璃棉(PMA-g-GW)混合物。使用过硫酸钾(PPS)和PPS /丙酮亚硫酸氢钠(ASBS)作为氧化还原对引发体系在60和70°C下进行聚合过程。使用PPS或PPS / ASBS对接枝率和转化率的影响表明,将PPS用作引发剂时的转化率值高于PPS / ASBS的值,而在接枝的情况下,则相反,也就是说,使用PPS作为引发剂所得到的接枝百分比值低于使用PPS / ASBS所能获得的百分比。接枝聚合过程中使用的PP的介电性能,热扩散系数,比热容和热导率随接枝聚合过程中使用的不同类型和浓度的引发剂(即PPS和氧化还原引发体系)的变化而变化研究。 (C)2002 Wiley Periodicals,Inc. [参考:21]

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