Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu-2(tpt)(bpy)(2)(H2O)(4)] [Cu-2(tpt)(3) (bpy)(2)(H2O)(2)]

Bu PY.; Zhang LZ.; Li LC.; Cheng P.; Yan SP.; Jiang ZH.; Liao DZ.

首页> 外文期刊>Journal of chemical crystallography >Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu-2(tpt)(bpy)(2)(H2O)(4)] [Cu-2(tpt)(3) (bpy)(2)(H2O)(2)]

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Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu-2(tpt)(bpy)(2)(H2O)(4)] [Cu-2(tpt)(3) (bpy)(2)(H2O)(2)]

机译：对苯二甲酸桥联铜（II）配合物[Cu-2（tpt）（bpy）（2）（H2O）（4）] [Cu-2（tpt）（3）（bpy）（2）的合成和晶体结构（H2O）（2）]

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A terephthalato-bridged copper(II) complex [Cu-2(tpt)(bpy)(2)(H2O)(4)][Cu-2(tpt)(3)(bpy)(2) (H2O)(2)] (1) (tpt = terephthalate, bpy = 2,2'-bipyridine) was synthesized by the reaction of Cu(ClO4)(2) . 6H(2)O and terephthalic acid in the presence of 2,2'-bipyridine in H2O solution. Crystal structure of 1 was determined by X-ray diffraction analysis in the triclinic space group P (1) over bar, with a = 10.7327(10) Angstrom, b = 11.1658(11) Angstrom, c = 17.3768(16) Angstrom, alpha = 108.063(2) degrees, beta = 91.064(2) degrees, gamma = 116.721(2) degrees, V = 1737.5(3) Angstrom(3), and Z = 2. Both the anion and the countercation in 1 are copper( II) complexes linked by terephthalate bridges in the bis(monodentate) (syn-anti) mode. The anion and the countercation are also linked by two hydrogen bonds between coordinating water molecules and terephthalate ligand. [References: 21]

机译：对苯二甲酸桥联铜（II）络合物[Cu-2（tpt）（bpy）（2）（H2O）（4）] [Cu-2（tpt）（3）（bpy）（2）（H2O）（2 ）]（1）（tpt =对苯二甲酸酯，bpy = 2,2'-联吡啶）是通过Cu（ClO4）（2）反应合成的。在2,2'-联吡啶存在下的H2O溶液中加入6H（2）O和对苯二甲酸。 1的晶体结构是通过X射线衍射分析确定的三边形空间群P（1）在棒上，a = 10.7327（10）埃，b = 11.1658（11）埃，c = 17.3768（16）埃= 108.063（2）度，β= 91.064（2）度，γ= 116.721（2）度，V = 1737.5（3）埃（3）和Z =2。1中的阴离子和抗衡阳离子均为铜（ II）通过对苯二甲酸酯桥以双（单齿）（顺-反）模式连接的复合物。阴离子和抗衡阳离子也通过配位水分子和对苯二甲酸酯配体之间的两个氢键连接。 [参考：21]

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《Journal of chemical crystallography》 |2003年第4期|共6页
作者
Bu PY.; Zhang LZ.; Li LC.; Cheng P.; Yan SP.; Jiang ZH.; Liao DZ.;
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正文语种 eng
中图分类晶体学;
关键词
Copper(ii) complex; Crystal structure; Terephthalate; 2; 2 '-bipyridine; Magnetic-properties; Framework; Compound; Chain; Ions;

机译：铜（ii）配合物;晶体结构;对苯二甲酸;2;2'-联吡啶;磁性;骨架;化合物;链;离子;

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1. Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu-2(tpt)(bpy)(2)(H2O)(4)] [Cu-2(tpt)(3) (bpy)(2)(H2O)(2)] [J] . Bu PY., Zhang LZ., Li LC., Journal of chemical crystallography . 2003,第4期

机译：对苯二甲酸桥联铜（II）配合物[Cu-2（tpt）（bpy）（2）（H2O）（4）] [Cu-2（tpt）（3）（bpy）（2）的合成和晶体结构（H2O）（2）]
2. Crystal structures of [Cu-2(bpy)(2)(H2O)(OH)(2)(SO4)] center dot 4H(2)O and [Cu(bpy)(H2O)(2)]SO4 with bpy=2,2 '-bipyridine [J] . Zheng YQ., Lin JL. Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第9期

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3. Crystal structure and magnetic properties of the flexible self-assembled two-dimensional square network complex [Cu-2(mal)(2)(H2O)(2)(4,4 '-I-bpy)] (H(2)mal = malonic acid and 4,4 '-bpy=4,4 '-bipyridine) [J] . Rodriguez-Martin Y., Sanchiz J., Lloret F., Inorganica Chimica Acta . 2001,第1a2期

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4. Synthesis and Crystal Structure of Quaternary Copper(Ⅱ) Complex with FluoroquinoloneLigand, Cu(cip)(bpy)Cl· 2H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：含氟喹诺酮配体Cu（cip）（bpy）Cl·2H2O的季铜（Ⅱ）配合物的合成和晶体结构
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6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

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机译：薄聚合物薄膜中水氧化催化剂（bpy）2（H2O）RuORu（H2O）2（4+）的氧化还原性质。 C1-至C12的电催化氧化

Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu-2(tpt)(bpy)(2)(H2O)(4)] [Cu-2(tpt)(3) (bpy)(2)(H2O)(2)]

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