Synthesis and crystal structure of bis(2-methylbenzimidazolium) tetrahalocuprate(II)

Bhattacharya R; Chanda S; Bocelli G; Cantoni A; Ghosh A

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Synthesis and crystal structure of bis(2-methylbenzimidazolium) tetrahalocuprate(II)

机译：四卤代双（2-甲基苯并咪唑鎓）的合成与晶体结构

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The crystal structures of 2-methylbenzimidazolium tetrahalocuprates (H2-mebz)(2)[CuX4] (X = Cl and Br) have been determined. The chloride salt is monoclinic, P2(1)/c, with a = 8.540(2) Angstrom, b = 16.591(2) Angstrom, c = 14.303(3) Angstrom, and beta = 98.69(2)degrees. The bromide salt is also monoclinic, P2(1)/c, with a = 8.316(3) Angstrom, b = 17.436(3) Angstrom, c = 14.747(3) Angstrom, and beta = 98.82(3)degrees. Both the compounds contain discrete distorted tetrahedral CuX42- anions and almost planar 2-methylbenzimidazolium cations. In the chloride salt, three chloride ions are involved in hydrogen bonding instead of two bromide ions in the bromide

机译：已经确定了2-甲基苯并咪唑四卤酸盐（H2-mebz）（2）[CuX4]（X = Cl和Br）的晶体结构。氯化物盐是单斜晶的，P2（1）/ c，a = 8.540（2）埃，b = 16.591（2）埃，c = 14.303（3）埃，β= 98.69（2）度。溴化物盐也是单斜晶的，P2（1）/ c，a = 8.316（3）埃，b = 17.436（3）埃，c = 14.747（3）埃，β= 98.82（3）度。两种化合物均包含离散的扭曲四面体CuX42-阴离子和几乎平面的2-甲基苯并咪唑鎓阳离子。在氯化物盐中，氢键涉及三个氯离子，而不是溴化物中的两个溴离子

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来源
《Journal of chemical crystallography》 |2004年第6期|共8页
作者
Bhattacharya R; Chanda S; Bocelli G; Cantoni A; Ghosh A;
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正文语种 eng
中图分类晶体学;
关键词
tetrahalocuprates; 2-methylbenzimidazolium cation; hydrogen bonding; crystal structures; TETRACHLOROCUPRATE(II); TETRABROMOCUPRATE(II);

机译：四卤代戊酸酯;2-甲基苯并咪唑阳离子;氢键键合;晶体结构;TETRACHLOROCUPRATE（II）;TETRABROMOCUPRATE（II）;

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Synthesis and crystal structure of bis(2-methylbenzimidazolium) tetrahalocuprate(II)

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