Synthesis, Structure and Luminescent Property of a Novel Lanthanide Metal-Organic Coordination Polymer Yb-3(BDC)(4.5)(DMF)(2)(H2O)(3) center dot (DMF)(2)

Na LY; Hua RN; Zhang LY; Zhang W; Ning GL

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Synthesis, Structure and Luminescent Property of a Novel Lanthanide Metal-Organic Coordination Polymer Yb-3(BDC)(4.5)(DMF)(2)(H2O)(3) center dot (DMF)(2)

机译：新型镧系金属有机配位聚合物Yb-3（BDC）（4.5）（DMF）（2）（H2O）（3）中心点（DMF）（2）的合成，结构和发光性能

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摘要

A three-dimensional lanthanide metal-organic coordination polymer Yb-3(BDC)(4.5)(DMF)(2)(H2O)(3) center dot (DMF)(2) has been synthesized by the reaction of the lanthanide metal ion (Yb3+) with 1,4-benzenedicarboxylic acid (H2BDC) under mild condition. The compound crystallizes in the triclinic system, space group PI with unit cell parameters a = 10.7428(9) angstrom, b = 11.2786(9) angstrom, c = 26.172(2) angstrom, alpha = 85.060(2)degrees, beta = 88.1060(10)degrees, gamma = 62.3670(10)degrees, V = 2798.9 (4) angstrom(3), Z = 2. The crystal structure exhibits one-dimensional channels along the [011] direction. The fluorescent results showed that there were two emission peaks at 375 and 420 nm when the compound was excited by a 235 nm excitation.

机译：通过镧系金属离子的反应合成了三维镧系金属有机配位聚合物Yb-3（BDC）（4.5）（DMF）（2）（H2O）（3）中心点（DMF）（2）（Yb3 +）与1,4-苯二甲酸（H2BDC）在温和条件下使用。该化合物在三斜晶系系统PI中结晶，其晶胞参数为a = 10.7428（9）埃，b = 11.2786（9）埃，c = 26.172（2）埃，alpha = 85.060（2）度，beta = 88.1060 （10）度，γ= 62.3670（10）度，V = 2798.9（4）埃（3），Z =2。晶体结构沿[011]方向显示一维通道。荧光结果表明，当化合物被235 nm激发时，在375和420 nm处有两个发射峰。

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来源
《Journal of chemical crystallography》 |2009年第9期|共4页
作者
Na LY; Hua RN; Zhang LY; Zhang W; Ning GL;
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正文语种 eng
中图分类晶体学;
关键词
Metal-organic coordination polymer; Lanthanide; Crystal structure; Luminescent property;

机译：金属有机配位聚合物;镧系元素;晶体结构;发光性能;

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1. Synthesis, Structure and Luminescent Property of a Novel Lanthanide Metal-Organic Coordination Polymer Yb-3(BDC)(4.5)(DMF)(2)(H2O)(3) center dot (DMF)(2) [J] . Na LY, Hua RN, Zhang LY, Journal of chemical crystallography . 2009,第9期

机译：新型镧系金属有机配位聚合物Yb-3（BDC）（4.5）（DMF）（2）（H2O）（3）中心点（DMF）（2）的合成，结构和发光性能
2. Synthesis, crystal structure, and magnetic properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}(n)center dot nDMF center dot nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer [J] . Zang SQ., Tao RJ., Wang QL., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第3期

机译：{[Cu（oxbe）] Mn（H2O）[Cu（oxbe）（DMF）]}（n）中心点nDMF中心点nH（2）O的合成，晶体结构和磁性能：从不对称单核实体到3D杂金属超分子配位聚合物
3. A novel 1D zigzag chain organic-inorganic polymer with Dawson-type polyoxometalates as building blocks: synthesis and crystal structure of H-1.5[Sm(H2O)(8)](0.5)[Sm(DMF)(6)(H2O)(alpha-P2W18O62)]center dot DMF center dot 3H(2)O [J] . Wang JP, Zhao JW, Niu JY Journal of Molecular Structure . 2004,第1a3期

机译：以Dawson型多金属氧酸盐为结构单元的新型一维曲折链有机-无机聚合物：H-1.5 [Sm（H2O）（8）]（0.5）[Sm（DMF）（6）（H2O）（ alpha-P2W18O62）]中心点DMF中心点3H（2）O
4. Synthesis, structure and properties of a novel metal-organic coordination polymer, Zn(NH_3)_2(BDC)_n [C] . Ning-ning Wu, Can-xiong Guo, Gui-an Wu International Congress on Advanced Materials . 2014

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5. Toward the Synthesis of Organic Moieties for use in Luminescent Lanthanide Materials: From Benzodithiophene Based Linkers to a Series of 2,3-Pyridinedicarboxylate Coordination Polymers. [D] . Ramirez, Amanda Lyn Staggers. 2013

机译：迈向用于发光镧系材料的有机部分的合成：从基于苯并二噻吩的连接剂到一系列2,3-吡啶二羧酸酯配位聚合物。
6. Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na2(3-chlorobenzoate)212-MCMn(III)N(shi)-4(DMF)6 and MnNa(3-chlorobenzoate)312-MCMn(III)N(shi)-4(DMF)(H2O)4·4DMF·0.72H2O [O] . Curtis M. Zaleski, Matthias Zeller 2020

机译：两种锰基12-金属镧4配合物的合成和晶体结构：Na2（3-氯苯甲酸酯）2 12-MCMn（III）N（shi）-4（DMF）6和MnNa（3-氯苯甲酸酯）3 12-MCMn（III）N（shi）-4（DMF）（H2O）4·4DMF·0.72H2O
7. Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na2(3-chlorobenzoate)212-MCMn(III)N(shi)-4(DMF)6 and MnNa(3-chlorobenzoate)312-MCMn(III)N(shi)-4(DMF)(H2O)4·4DMF·0.72H2O [O] . Curtis M. Zaleski, Matthias Zeller 2020

机译：两种基于锰的12-金属酰胺-4络合物的合成和晶体结构：Na 2（3-氯苯甲酸盐）2 12-MCMN（III）N（SHI）-4（DMF）6和MNNA（3-氯苯甲酸盐）3 12-MCMN（III）N（SHI）-4（DMF）（H2O）4·4DMF·0.72H2O

Synthesis, Structure and Luminescent Property of a Novel Lanthanide Metal-Organic Coordination Polymer Yb-3(BDC)(4.5)(DMF)(2)(H2O)(3) center dot (DMF)(2)

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