One-pot synthesis, crystal structures and topology analysis of two nickel(II) complexes based on 1,3,5-benzenetricarboxylic acid

Zhao Y.-N.; Wang Y.-Y.; Zhao Y.-Q.; Cui G.-H.

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One-pot synthesis, crystal structures and topology analysis of two nickel(II) complexes based on 1,3,5-benzenetricarboxylic acid

机译：基于1,3,5-苯三甲酸的两种镍（II）配合物的一锅合成，晶体结构和拓扑分析

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The one-pot solvothermal reaction of Ni(NO_3)_2 with 1,3,5-benzenetricarboxylic acid (H3btc) and 4,4-bis(imidazol-1-yl) benzene (bibp) affords two coordination compounds. The H3btc ligand is deprotonated step-by-step, and connects NiII ions into two different valence-bonded structures (the binuclear molecule and 2D (4,4) grid) under the cooperation of bibp. Hydrogen bonds have been deeply investigated, and yield an interpenetrating binodal (3,5)-connected supramolecular network with the Sch?fli symbol of [4~2.6]·[4~2.6~5.8~3] and interdigitating binodal (4,6)-connected supramolecular network with the Sch?fli symbol of [4~4.5~2]·[4~4.5~6.6~4.7], respectively.

机译：Ni（NO_3）_2与1,3,5-苯三羧酸（H3btc）和4,4-双（咪唑-1-基）苯（bibp）的一锅溶剂热反应提供了两种配位化合物。 H3btc配体逐步去质子化，并在bibp的协作下将NiII离子连接到两个不同的价键结构（双核分子和2D（4,4）网格）中。已对氢键进行了深入研究，并产生了一个相互贯穿的双链体（3,5）连接的超分子网络，其Sch？fli符号为[4〜2.6]·[4〜2.6〜5.8〜3]和指叉双齿体（4,6 ）连接的超分子网络，其Sch？fli符号分别为[4〜4.5〜2]·[4〜4.5〜6.6〜4.7]。

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《Journal of chemical crystallography》 |2013年第9期|共6页
作者
Zhao Y.-N.; Wang Y.-Y.; Zhao Y.-Q.; Cui G.-H.;
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正文语种 eng
中图分类 54.9;
关键词
Complexes; One-pot synthesis; Supramolecular network; Topology analysis;

机译：配合物;一锅合成;超分子网络;拓扑分析;

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1. One-pot synthesis, crystal structures and topology analysis of two nickel(II) complexes based on 1,3,5-benzenetricarboxylic acid [J] . Zhao Y.-N., Wang Y.-Y., Zhao Y.-Q., Journal of chemical crystallography . 2013,第9期

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One-pot synthesis, crystal structures and topology analysis of two nickel(II) complexes based on 1,3,5-benzenetricarboxylic acid

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