Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) generates a discrete complex not a coordination polymer: crystal structure of [mu-4,4 '-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N,O,O '-mu-N ',O '',O ''']-diaqua-

Wang Y; Cooper CGF; Luisi BS; Moulton B; MacDonald JC

首页> 外文期刊>Journal of chemical crystallography >Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) generates a discrete complex not a coordination polymer: crystal structure of [mu-4,4 '-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N,O,O '-mu-N ',O '',O ''']-diaqua-

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Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) generates a discrete complex not a coordination polymer: crystal structure of [mu-4,4 '-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N,O,O '-mu-N ',O '',O ''']-diaqua-

机译：1,2-双（2,6-二羧基吡啶基-4-基）乙炔和咪唑与Cu（II）反应生成离散的复合物而不是配位聚合物：[mu-4,4'-（1,2 -乙炔二基）-双（吡啶-2,6-二羧酸基）-N，O，O'-mu-N'，O''，O''']-透水-

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Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl) ethyne and imidazole with Cu(II) produces crystals containing a discrete complex of [mu-4,4'-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)- N, O, O'-mu- N', O '', O''']-diaqua-bis(imidazole)-dicopper(II) complex ( 1), [(C16H4N2O8)(C3H4N2)(2)(H2O)(2)Cu-2] instead of a linear coordination polymer. The complex crystallizes in themonoclinic space group P2(1) with a = 5.3763( 8) angstrom, b = 18.522(3) angstrom, c = 11.4827( 7) angstrom, beta = 93.705(3)degrees and Z = 2. The complex sits on a center of symmetry such that the two halves of the molecule are related by inversion symmetry. The molecules pack in layers in which the molecules are joined by intermolecular N - H center dot center dot center dot O hydrogen bonds between imidazole and carboxylate groups and O - H center dot center dot center dot O hydrogen bonds between carboxylate groups and water.

机译：1,2-双（2,6-二羧基吡啶基-4-基）乙炔和咪唑与Cu（II）反应生成晶体，该晶体包含[mu-4,4'-（1,2-乙炔二基）-bis的离散复合物（吡啶-2,6-二羧基戊基）-N，O，O'-mu-N'，O''，O''']-二氨基-双（咪唑）-二铜（II）配合物（1），[[ C16H4N2O8）（C3H4N2）（2）（H2O）（2）Cu-2]代替线性配位聚合物。该复合物在单斜空间群P2（1）/ n中以a = 5.3763（8）埃，b = 18.522（3）埃，c = 11.4827（7）埃，beta = 93.705（3）度和Z = 2结晶。络合物位于对称中心，因此分子的两半通过反对称对称。分子堆积在其中分子通过咪唑和羧酸酯基团之间的分子间N-H中心点中心点中心点O氢键和羧酸酯基团和水之间的OH-中心点中心点中心点O氢键连接的层中。

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《Journal of chemical crystallography》 |2007年第4期|共10页
作者
Wang Y; Cooper CGF; Luisi BS; Moulton B; MacDonald JC;
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正文语种 eng
中图分类晶体学;
关键词
2; 6-dicarboxypyridine; 1; 2-bis(2; 6-dicarboxypyridin-4-yl)ethyne; imidazole; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; GRAPH-SET ANALYSIS; POROUS FRAMEWORK; GUEST ADSORPTION; HYDROGEN-BONDS; DESIGN; SORPTION; CARBOXYLATES; TEMPERATURE;

机译：2;6-二羧基吡啶;1;2-双（2;6-二羧基吡啶-4-基）乙炔;咪唑;金属有机骨架;二级建筑;图形集分析;多孔骨架;客体吸附;氢键;设计;吸附;羧酸盐;温度;

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1. Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) generates a discrete complex not a coordination polymer: crystal structure of [mu-4,4 '-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N,O,O '-mu-N ',O '',O ''']-diaqua- [J] . Wang Y, Cooper CGF, Luisi BS, Journal of chemical crystallography . 2007,第4期

机译：1,2-双（2,6-二羧基吡啶基-4-基）乙炔和咪唑与Cu（II）反应生成离散的复合物而不是配位聚合物：[mu-4,4'-（1,2 -乙炔二基）-双（吡啶-2,6-二羧酸基）-N，O，O'-mu-N'，O''，O''']-透水-
2. Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne with Co(II) generates coordination monomers not polymers: Crystal structure of 4-(2,6-dicarboxypyridin-4-yl)ethynylpyridine-2,6-dicarboxylatotriaqua cobalt(II) monohydrate [J] . Yigit MV, Cooper CGF, Wang Y, Journal of chemical crystallography . 2006,第6期

机译：1,2-双（2,6-二羧基吡啶基-4-基）乙炔与Co（II）反应生成配位单体而不是聚合物：4-（2,6-二羧基吡啶基-4-基）乙炔基吡啶-2的晶体结构， 6-二羧基latotriaqua一水合钴（II）
3. Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne with Co(II) generates coordination monomers not polymers: Crystal structure of 4-(2,6-dicarboxypyridin-4-yl)ethynylpyridine-2,6-dicarboxylatotriaqua cobalt(II) monohydrate [J] . Mehmet V. Yigit, Christopher G. F. Cooper, Yu Wang, Journal of Chemical Crystallography . 2006,第6期

机译：1,2-双（2,6-二羧基吡啶基-4-基）乙炔与Co（II）反应生成配位单体而不是聚合物：4-（2,6-二羧基吡啶基-4-基）乙炔基吡啶-2的晶体结构， 6一水二羧酸二钴钴（II）
4. Synthesis,Crystal structure and DNA Binding of of a chiral new Cu(II) complex with (1R, 2R)-1,2-hexanediamine [C] . Yinzhi Jiang, Zhenyu Chen, Liangqun Zhang MEMC 2013 . 2013

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机译：CCDC 860714：实验晶体结构测定：联萘-[双（二甲基铵）双（mu-5,5'-乙炔-1,2-二基二间苯二甲酸酯）-二铟N，N-二甲基甲酰胺溶剂化物]
7. Phase Transfer Pd(O) Catalyzed Polymerization Reactions. 1. Synthesis of 1,2-(4,4'-Dialkoxyaryl)Acetylene Monomers and 1,4-Bis(2-(4',4''-Dialkoxyphenyl)Ethynyl)Benzene Derivatives by Phase Transfer Pd(O)/Cu(I) Catalyzed Coupling Reactions. [R] . Pugh, C., Percec, V. 1990

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Reaction of 1,2-bis(2,6-dicarboxypyridin-4-yl)ethyne and imidazole with Cu(II) generates a discrete complex not a coordination polymer: crystal structure of [mu-4,4 '-(1,2-ethynediyl)-bis(pyridine-2,6-dicarboxylato)-N,O,O '-mu-N ',O '',O ''']-diaqua-

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