X-ray structure of mer-[Mo(CO)_3(PPh_3) (κ~2-dppm)]

Ghosh S.; Kabir S.E.; Camellia F.K.; Hossain M.K.; Haworth D.T.; Lindeman S.V.; Siddiquee T.A.; Bennett D.W.

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X-ray structure of mer-[Mo(CO)_3(PPh_3) (κ~2-dppm)]

机译：mer- [Mo（CO）_3（PPh_3）（κ〜2-dppm）]的X射线结构

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Treatment of [Mo(CO)_3(NCMe)_3] with bis (diphenylphosphino)methane (dppm) and triphenylphosphine (PPh_3) at 50 °C afforded mer-[Mo(CO)_3(PPh_3) (κ~2- dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P-1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) ?, b = 80.8400(10)°, Z = 2 and V = 1959.8(2) ? 3.

机译：在50°C下用双（二苯基膦基）甲烷（dppm）和三苯基膦（PPh_3）处理[Mo（CO）_3（NCMe）_3]，得到mer- [Mo（CO）_3（PPh_3）（κ〜2- dppm） ]（1）以单晶X射线衍射研究和光谱测量为特征，产率为55％。化合物1在三斜空间群P-1中结晶，其a = 10.3449（6），b = 11.1570（6），c = 17.8961（10）α，b = 80.8400（10）°，Z = 2和V = 1959.8（ 2）？ 3。

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《Journal of chemical crystallography》 |2010年第8期|共4页
作者
Ghosh S.; Kabir S.E.; Camellia F.K.; Hossain M.K.; Haworth D.T.; Lindeman S.V.; Siddiquee T.A.; Bennett D.W.;
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正文语种 eng
中图分类晶体学;
关键词
Bis(diphenylphosphino) methane; Molybdenum; Triphenylphosphine; X-ray structure;

机译：双（二苯基膦基）甲烷;钼;三苯基膦;X射线结构;

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1. X-ray structure of mer-[Mo(CO)_3(PPh_3) (κ~2-dppm)] [J] . Ghosh S., Kabir S.E., Camellia F.K., Journal of chemical crystallography . 2010,第8期

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X-ray structure of mer-[Mo(CO)_3(PPh_3) (κ~2-dppm)]

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