The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)]center dot 4H(2)O

Xie CZ; Zhang BF; Wang XQ; Wang RJ; Shen GQ; Shen DZ

首页> 外文期刊>Journal of chemical crystallography >The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)]center dot 4H(2)O

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The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)]center dot 4H(2)O

机译：新型交替一维钴配位聚合物[Co（2,5-PDC）（2）（H2O）（2）Co（H2O）（4）]中心点4H（2）O的合成与结构

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A novel cobalt complex [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)](.)4H(2)O (2,5-PDCH2 = 2,5-pyridinedicarboxylic acid) was synthesized and its crystal structure has been determined by X-ray diffraction. The crystallographic data are: triclinic P-1, a = 7.112(2) angstrom, b = 8.939(3) angstrom, c = 9.719(3) angstrom, alpha = 91.153(5)degrees, beta = 101.136(5)degrees, gamma = 108.001(4)degrees, V = 574.4(3) angstrom(3), Z = 1. The compound [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)](.)4H(2)O exhibits a novel one-dimensional network constructed from the interconnection of Co(2,5-PDC)(2)(H2O)(2) and Co(H2O)(4), in which two kinds of six-coordinated Co(II) atoms have both octahedral coordination environments. Each 2,5-PDC anion connects two different coordinated cobalt ions alternately in an one-dimensional chain. The zigzag 1D alternating chains are linked by extensive hydrogen bonds to form a three-dimensional (3D) supramolecular structure, in which uncoordinated solvate molecules act as space filling particles.

机译：新型钴络合物[Co（2,5-PDC）（2）（H2O）（2）Co（H2O）（4）] .. 4H（2）O（2,5-PDCH2 = 2,5-吡啶二羧酸合成），并通过X射线衍射确定其晶体结构。晶体学数据为：三斜晶系P-1，a = 7.112（2）埃，b = 8.939（3）埃，c = 9.719（3）埃，α= 91.153（5）度，beta = 101.136（5）度， γ= 108.001（4）度，V = 574.4（3）埃（3），Z =1。化合物[Co（2,5-PDC）（2）（H2O）（2）Co（H2O）（4） ]（。）4H（2）O展示了一种由Co（2,5-PDC）（2）（H2O）（2）和Co（H2O）（4）相互连接构成的新型一维网络六配位的Co（II）原子都具有八面体配位环境。每个2，5-PDC阴离子在一维链中交替连接两个不同的配位钴离子。之字形1D交替链通过广泛的氢键连接，形成三维（3D）超分子结构，其中未配位的溶剂化物分子充当空间填充颗粒。

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《Journal of chemical crystallography》 |2007年第1期|共5页
作者
Xie CZ; Zhang BF; Wang XQ; Wang RJ; Shen GQ; Shen DZ;
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正文语种 eng
中图分类晶体学;
关键词
crystal structure; cobalt complex; 1D alternating chain; pyridine-2; 5-dicarboxylic acid; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; MAGNETIC-PROPERTIES; COMPLEXES; ACID; NICKEL(II); CHEMISTRY; COMPOUND; CHAINS; SERIES;

机译：晶体结构;钴配合物;一维交替链;吡啶-2;5-二羧酸;晶体结构;水热合成;磁性能;络合物;酸;镍（II）;化学性质;化合物;链;系列;

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1. The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)]center dot 4H(2)O [J] . Xie CZ, Zhang BF, Wang XQ, Journal of chemical crystallography . 2007,第1期

机译：新型交替一维钴配位聚合物[Co（2,5-PDC）（2）（H2O）（2）Co（H2O）（4）]中心点4H（2）O的合成与结构
2. Hydrothermal synthesis and crystal structure of a novel 2-D coordination polymer [Mn-2(pdc)(2)(H2O)(3)](n)center dot 2n H2O (pdc = pyridine-2,3-dicarboxylate) [J] . Li LJ, Li Y Journal of Molecular Structure . 2004,第1a3期

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3. New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)(2)(H2O)(2)]L center dot 4H(2)O, Mn(phen)(H2O)(2)L and Zn(phen)L center dot H2L with-H2L fumaric acid [J] . Zheng YQ., Lin JL., Chen BY. Journal of Molecular Structure . 2003,第1a3期

机译：使用富马酸酯配体作为桥间隔基的新型链状配位聚合物：[Mn（phen）（2）（H2O）（2）] L中心点4H（2）O，Mn（phen）（H2O）（2）L和Zn（phen）L中心点H2L与-H2L富马酸
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

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5. Synthesis, Structure and Catalytic Application of Silver (I) Coordination Polymers Based on 1,2,4,5-Tetra(Isopropylthio)Benzene Ligand [D] . Kakumanu, Srinija. 2017

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6. Synthesis and Anti-Candida Activity of Cobalt(II) Complexes ofBenzene-12-Dioxyacetic Acid (bdoaH2). X-Ray Crystal Structures of Co(bdoa)(H2O)3⋅3.5H2O and {CO(phen)3(bdoa)}2⋅24H2O (phen = 110-Phenanthroline) [O] . Majella Geraghty, Malachy McCann, Michael Devereux, 1999

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8. Model Compound Studies of Rigid Rod Aromatic Heterocyclic Polymer Systems, the X-Ray Crystal Structure of 2,6-Diphenylbenzo (1,2-d; 5,4-d') Diimidazole Tetrahydrate, C2OH14N4. 4H2O, a Model System for the Study of Polymer-Water Interaction in Polybenzimidazoles. [R] . Hunsaker, M., Adams, W. W., Fratini, A. V. 1983

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The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)(2)(H2O)(2)Co(H2O)(4)]center dot 4H(2)O

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