Synthesis, Structure and Characterization of Two 1D Chain-like Cadmium Terephthalate Complexes: [Cd(tp)(H2O)(3)] center dot 4H(2)O and [Ph4P][Cd(tp)(0.5)Cl-2] center dot H2O

Lian YX; Yang GD; Dai JC; Fu ZY; Wu XT

首页> 外文期刊>Journal of chemical crystallography >Synthesis, Structure and Characterization of Two 1D Chain-like Cadmium Terephthalate Complexes: [Cd(tp)(H2O)(3)] center dot 4H(2)O and [Ph4P][Cd(tp)(0.5)Cl-2] center dot H2O

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Synthesis, Structure and Characterization of Two 1D Chain-like Cadmium Terephthalate Complexes: [Cd(tp)(H2O)(3)] center dot 4H(2)O and [Ph4P][Cd(tp)(0.5)Cl-2] center dot H2O

机译：两种一维链状对苯二甲酸镉镉配合物的合成，结构和表征：[Cd（tp）（H2O）（3）]中心点4H（2）O和[Ph4P] [Cd（tp）（0.5）Cl-2]中心点H2O

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Two new compounds, [Cd(tp)(H2O)(3)] center dot 4H(2)O (1) and [Ph4P][Cd (tp)(0.5)Cl-2] center dot H2O (2) (tp = terephthalate, [Ph4P] = tetraphenylphosphonium), are metal-poly-carboxylate coordination polymers prepared by similar hydrothermal synthesis techniques. Both compounds crystallize in the 1D chain-like architectures. 1 (C8H18 CdO11) is orthorhombic Pcca, Z = 4 (a = 7.3018(1) angstrom, b = 9.9975(3) angstrom, c = 19.9695(5) angstrom, V = 1457.77(6) angstrom(3)). 2 (C28H24CdCl2O3P) is triclinic P-1, Z = 2 (a = 9.5028(4)angstrom, b = 12.3130(5)angstrom, c = 12.7343(6)angstrom, alpha = 68.380(1)degrees, beta = 73.723(1)degrees, gamma = 89.624(1)degrees, V = 1321.8(1)angstrom(3)). Transition metal cadmium centers bridged by rigid linear tp ligands give rise to a 1D infinite zigzag chain polymer for 1 and a simple 1D infinite stepped chain polymer for 2.1 presents an interesting plywood-like packing network while 2 shows a simple parallel rod-like stacking network. An intense fluorescent emission at 412 nm (lambda(exc) = 338 nm) for 1 in the solid state at room temperature is observed.

机译：两种新化合物[Cd（tp）（H2O）（3）]中心点H2O（2）（t）和[Ph4P] [Cd（tp）（0.5）Cl-2]中心点H2O（2）（tp ＝对苯二甲酸酯，[Ph 4 P] ＝四苯基phosph，是通过类似的水热合成技术制备的金属-聚羧酸盐配位聚合物。两种化合物均以一维链状结构结晶。 1（C8H18 CdO11）是正交晶体Pcca，Z = 4（a = 7.3018（1）埃，b = 9.9975（3）埃，c = 19.9695（5）埃，V = 1457.77（6）埃（3））。 2（C28H24CdCl2O3P）是三斜晶P-1，Z = 2（a = 9.5028（4）埃，b = 12.3130（5）埃，c = 12.7343（6）埃，alpha = 68.380（1）度，beta = 73.723（ 1）度，伽玛= 89.624（1）度，V = 1321.8（1）埃（3））。刚性线性tp配体桥接的过渡金属镉中心产生1的1D无限之字形链聚合物，而2.1的简单1D无限阶梯链聚合物表现出有趣的胶合板状堆积网络，而2则显示出简单的平行杆状堆积网络。在室温下，对于固态的1，在412 nm（λ（exc）= 338 nm）处观察到强烈的荧光发射。

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来源
《Journal of chemical crystallography》 |2009年第1期|共8页
作者
Lian YX; Yang GD; Dai JC; Fu ZY; Wu XT;
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正文语种 eng
中图分类晶体学;
关键词
Crystal structure; Coordination polymer; Cadmium terephthalate complexe; 1D infinite chain; Hydrothermal synthesis;

机译：晶体结构配位聚合物对苯二甲酸镉络合物一维无穷链水热合成;

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1. Synthesis, Structure and Characterization of Two 1D Chain-like Cadmium Terephthalate Complexes: [Cd(tp)(H2O)(3)] center dot 4H(2)O and [Ph4P][Cd(tp)(0.5)Cl-2] center dot H2O [J] . Lian YX, Yang GD, Dai JC, Journal of chemical crystallography . 2009,第1期

机译：两种一维链状对苯二甲酸镉镉配合物的合成，结构和表征：[Cd（tp）（H2O）（3）]中心点4H（2）O和[Ph4P] [Cd（tp）（0.5）Cl-2]中心点H2O
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Synthesis, Structure and Characterization of Two 1D Chain-like Cadmium Terephthalate Complexes: [Cd(tp)(H2O)(3)] center dot 4H(2)O and [Ph4P][Cd(tp)(0.5)Cl-2] center dot H2O

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