Crystal Structure of Tetraphenylarsonium Diisothiocyanatodichlorocobaltate(II)

Prasad RS; Thomas J; Jha NK

首页> 外文期刊>Journal of chemical crystallography >Crystal Structure of Tetraphenylarsonium Diisothiocyanatodichlorocobaltate(II)

【24h】

Crystal Structure of Tetraphenylarsonium Diisothiocyanatodichlorocobaltate(II)

机译：四苯基ar二异硫氰基二氯钴酸盐的晶体结构（II）

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Tetraphenylarsonium diisothiocyanatodichlorocobaltate(II) was synthesized by metathetic pathway. It crystallizes in the monoclinic space group C 2/c with unit cell parameters, a = 13.510(4) , b = 15.873(5) , c = 22.809(7) , beta = 105.743(6)A degrees, V = 1,618(5) (3) and Z = 4. X-ray crystal structure analysis reveals that the asymmetric unit contains one {(C6H5)(4)As}(+) cation and one half {Co(NCS)(2)Cl-2}(2-) anion, the latter lying on a crystallographic twofold axis. While each {Co(NCS)(2)Cl-2}(2-) anion exhibits hydrogen bonding interactions with eight arsonium cations; CH center dot center dot center dot pi interactions between phenyl rings of arsonium cations is restricted to two such centers in the crystal structure.

机译：通过易位途径合成了四苯基二异氰基氰基二氯钴盐（II）。它在单斜晶空间群C 2 / c中以晶胞参数结晶，a = 13.510（4），b = 15.873（5），c = 22.809（7），beta = 105.743（6）A度，V = 1,618（ 5）（3）和Z =4。X射线晶体结构分析表明，该不对称单元包含一个{{C6H5）（4）As}（+）阳离子和一半{Co（NCS）（2）Cl-2 }（2-）阴离子，后者位于晶体学双重轴上。尽管每个{Co（NCS）（2）Cl-2}（2-）阴离子都与八个砷阳离子表现出氢键相互作用;砷阳离子的苯环之间的CH中心点中心点中心点pi相互作用限于晶体结构中的两个这样的中心。

著录项

来源
《Journal of chemical crystallography》 |2010年第2期|共4页
作者
Prasad RS; Thomas J; Jha NK;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Structure; Tetraphenylarsonium; Diisothiocyanatodichlorocobaltate;

机译：结构;四苯基ar;二异硫氰基二氯钴酸酯;

相似文献

外文文献
中文文献
专利

1. Crystal Structure of Tetraphenylarsonium Diisothiocyanatodichlorocobaltate(II) [J] . Prasad RS, Thomas J, Jha NK Journal of chemical crystallography . 2010,第2期

机译：四苯基ar二异硫氰基二氯钴酸盐的晶体结构（II）
2. Crystal and Molecular Structure of Tetraphenylarsonium Diiodobromide [J] . M. S. Chernovyants, I. V. Burykin, N. V. Aleshina Russian Journal of General Chemistry . 2008,第7期

机译：四苯基ar二碘溴化物的晶体和分子结构
3. Synthesis, crystal structure, and magnetic properties of tetraphenylarsonium tetrachloro(oxalato)rhenate(IV) and bis (2,2 '-bipyridine)tetrachloro(mu-oxalato)copper(II)rhenium(IV) [J] . Chiozzone R., Kremer C., De Munno G., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第21期

机译：四氯ar杂草酸酯（IV）和双（2,2'-联吡啶）四氯mu杂草酸铜（II）r的四苯基ar的合成，晶体结构和磁性
4. ABOUT TERAHERTZ GENERATION ON THE SUPERSTRUCTURES LAYERS A~(III)B~(III)C_2~(VI) CRYSTALS [C] . R.M.Sardarly, O.A.Samedov, A.A.Bayramov, IMECE2009;ASME international mechanical engineering congress and exposition . 2010

机译：关于A〜（III）B〜（III）C_2〜（VI）晶体上层的TERAHERTZ生成
5. I. CRYSTAL AND MOLECULAR STRUCTURE OF ANTITUMOR AGENT JATROPHATRIONE; II. CRYSTAL AND MOLECULAR STRUCTURES OF TWO PYRIMIDONE DIMERS; III. CRYSTAL AND MOLECULAR STRUCTURE OF PHTHALIC ANHYDRIDE; IV. SYNTHETIC STUDIES ON THE SIDE CHAINS OF CEPHALOTAXINE ESTERS, POTENT ANTICANCER AGENTS. [D] . CUTLER, ROBERT STEVEN -1

机译：一，抗老剂麻油酮的晶体和分子结构；二。两种嘧啶酮的晶体和分子结构；三，邻苯二甲酸酐的晶体和分子结构； IV。头孢洛辛酯，强效抗癌剂的侧链合成研究。
6. Crystal structures of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) monohydrate and fac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs [O] . Joseph S. Merola, Marion A. Franks 2015

机译：fac-三氯代三（三甲基膦-κP）铑（III）一水合物的晶体结构和fac-三氯代三（3-甲基膦-κP）铑（III）甲醇半溶剂化物的铑结构：与铱类似物同型的铑结构
7. Neutral and anionic derivatives of toluene-3,4-dithiolatocadmium(II); the crystal structure of di(tetraphenylarsonium) bis(toluene-3,4-dithiolato)cadmate(II) [O] . Luis Bustos, Masood A. Khan, Dennis G. Tuck 1983

机译：甲苯-3,4-二硫代啶（II）的中性和阴离子衍生物; DI（四苯基锡）双（甲苯-3,4-二硫醇）载体（II）的晶体结构
8. Microscopic Optical Characterization of Free Standing III-Nitride Substrates, ZnO Bulk Crystals, and III-V Structures for Non-Linear Optics. [R] . Jimenez, J., Hortelano, V., Martinez, O., 2013

机译：用于非线性光学元件的独立式III-氮化物衬底，ZnO块状晶体和III-V结构的微观光学表征。

Crystal Structure of Tetraphenylarsonium Diisothiocyanatodichlorocobaltate(II)

摘要

著录项

相似文献

相关主题

期刊订阅