Crystal Structure and Thermodecomposition Kinetics of Mn(II) Complex with 1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazolone

Yang LR; Shao CY; Wang ZL; Liu JT; Zhou LF

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Crystal Structure and Thermodecomposition Kinetics of Mn(II) Complex with 1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazolone

机译：Mn（II）与1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazolone的配合物的晶体结构和热分解动力学

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The complex [Mn(PMBP)(2)(CH3OH)(2)] of manganese(II) with 1-phenyl-3-methyl- 4-benzoyl-5-pyrazolone (PMBP) was prepared and characterized by elemental analysis, thermal analysis, IR. The crystal structure of the complex determined by single crystal X-ray analysis, indicates that PMBP is a bidentate ligand in the complex and Mn(II) atom is six-coordinated and is in a meridional octahedral environment. The compound crystallizes in the monoclinic system, space group P-2(1)/c, with a = 11.038(10) angstrom, b = 16.254(15) angstrom, c = 9.540(9) angstrom, alpha = 90.00 degrees, b = 105.112(10)degrees, c = 90.00 degrees, V = 1,652(3) angstrom(3), D-x = 1.354 g cm(-3) and Z = 2. The thermal decomposition kinetics of the complex was investigated under nonisothermal conditions using the Achar differential method and the Coats-Redfern integral method.

机译：制备了锰（II）与1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮（PMBP）的配合物[Mn（PMBP）（2）（CH3OH）（2）]，并通过元素分析，热分析进行了表征分析，红外。通过单晶X射线分析确定的配合物的晶体结构表明，PMBP是配合物中的二齿配体，并且Mn（II）原子是六配位的并且处于子午八面体环境中。该化合物在单斜晶系空间群P-2（1）/ c中结晶，a = 11.038（10）埃，b = 16.254（15）埃，c = 9.540（9）埃，alpha = 90.00度，b = 105.112（10）度，c = 90.00度，V = 1,652（3）埃（3），Dx = 1.354 g cm（-3），Z =2。在非等温条件下，使用Achar微分法和Coats-Redfern积分法。

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《Journal of chemical crystallography》 |2010年第1期|共6页
作者
Yang LR; Shao CY; Wang ZL; Liu JT; Zhou LF;
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正文语种 eng
中图分类晶体学;
关键词
Crystal structure; Pyrazolone; Thermodecomposition kinetics;

机译：晶体结构;吡唑啉酮;热模组成动力学;

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Crystal Structure and Thermodecomposition Kinetics of Mn(II) Complex with 1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazolone

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