In situ assembly of a host-guest linked, mixed valence copper(II)-copper(I) coordination polymer [Cu(l,2-en)_2μ_3-I)_2Cu_2(μ_2-I)_2]_n via partial reduction of copper(II) under ambient conditions

SUBRATA JANA; KLAUS HARMS; SHOUVIK CHATTOPADHYAY

首页> 外文期刊>Journal of Coordination Chemistry >In situ assembly of a host-guest linked, mixed valence copper(II)-copper(I) coordination polymer [Cu(l,2-en)_2μ_3-I)_2Cu_2(μ_2-I)_2]_n via partial reduction of copper(II) under ambient conditions

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In situ assembly of a host-guest linked, mixed valence copper(II)-copper(I) coordination polymer [Cu(l,2-en)_2μ_3-I)_2Cu_2(μ_2-I)_2]_n via partial reduction of copper(II) under ambient conditions

机译：通过部分还原铜原位连接原位客体连接的混合价态铜（II）-铜（I）配位聚合物[Cu（l，2-en）_2μ_3-I）_2Cu_2（μ_2-I）_2] _n （二）在环境条件下

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A 2-D coordination polymer, [Cu(l,2-en)_2μ_3-I)_2Cu_2(μ_2-I)_2]_n (1),was formed at room temperature by in situ insertion of [Cu(l,2-en)_2]~(2+) guests into 1-D chains of a [Cu_2I_4]~(2-) host [l,2-en= 1,2-diami-noethane]. The structure of the complex was confirmed by single-crystal X-ray diffraction study. The shortest copper(I)-copper(I) distance within the complex is 2.89 A.

机译：在室温下，通过原位插入[Cu（l，2-]形成2-D配位聚合物[Cu（l，2-en）_2μ_3-I）_2Cu_2（μ_2-I）_2] _n（1）。 en）_2]〜（2+）位宾客进入[Cu_2I_4]〜（2-）主体[1,2-en = 1,2-二氨基-乙烷]的1-D链。通过单晶X射线衍射研究证实了该配合物的结构。配合物中最短的铜（I）-铜（I）距离为2.89 A.

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《Journal of Coordination Chemistry》 |2014年第18期|共13页
作者
SUBRATA JANA; KLAUS HARMS; SHOUVIK CHATTOPADHYAY;
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正文语种 eng
中图分类无机化学;
关键词
Copper(II); Copper(I); μ_3-I; Crystal structure; Coordination polymer;

机译：铜（II）;铜（I）;μ_3-I;晶体结构;配位聚合物;

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1. In situ assembly of a host-guest linked, mixed valence copper(II)-copper(I) coordination polymer [Cu(l,2-en)_2μ_3-I)_2Cu_2(μ_2-I)_2]_n via partial reduction of copper(II) under ambient conditions [J] . SUBRATA JANA, KLAUS HARMS, SHOUVIK CHATTOPADHYAY Journal of Coordination Chemistry . 2014,第17a18期

机译：通过部分还原铜原位连接原位客体连接的混合价态铜（II）-铜（I）配位聚合物[Cu（l，2-en）_2μ_3-I）_2Cu_2（μ_2-I）_2] _n （二）在环境条件下
2. Formation of a mixed valence copper(II)-copper(I) coordination polymer {[Cu(1,2-pn)_2(μ_3-I)Cu_2(μ_2-I)_3(CH_3CN)] CH_3CN}_n: in situ reduction of copper(II) at ambient condition [J] . SUBRATA JANA, SHOUVIK CHATTOPADHYAY Journal of Coordination Chemistry . 2013,第21a22期

机译：混合价铜（II）-铜（I）配位聚合物{[Cu（1,2-pn）_2（μ_3-I）Cu_2（μ_2-I）_3（CH_3CN）] CH_3CN} _n的形成：原位还原环境条件下铜（II）的数量
3. Ferromagnetic copper(II)-copper(II) interaction in a single chlorido and dicyanamido bridged mixed-valence copper(I/II) 2-D polymer generated by in situ partial reduction of copper(II) [J] . Nandy Madhusudan, Shit Shyamapada, Dhal Piu, Journal of Coordination Chemistry . 2015,第5a6期

机译：原位部分还原铜（II）生成的单氯离子与双氰胺桥联的混合价铜（I / II）2-D聚合物中的铁磁性铜（II）-铜（II）相互作用
4. Synthesis and Crystal Structure of a New Copper(II) Coordination Polymer Cu(II)C_(16) H_(18) N_4O_4S_n [C] . LI Jia-gui, ZHU Wan-ren, DING Shu-hong, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：新型铜（II）配位聚合物的合成和晶体结构Cu（II）C_（16）H_（18）N_4O_4S _N
5. Chemistry of copper peptide complexes: Alkoxide coordination in copper(II) and copper(III) peptide complexes, and base decomposition of copper(III) peptide complexes [D] . Wang, Lihua. 1991

机译：铜肽络合物的化学：铜（II）和铜（III）肽络合物中的醇配位，以及铜（III）肽络合物的碱分解
6. Electrochemical Synthesis and Structural Characterization of a Novel Mixed-valence Copper (I)-copper (II) Complex: {Bis(ethylenediamine) Copper (II) Bisdiiodocuprate (I)} [O] . Lida Fotouhi, Saeed Dehghanpour, Majid M. Heravi, 2007

机译：新型混合价铜（I）-铜（II）配合物的电化学合成和结构表征：{双（乙二胺）铜（II）双二碘多丁酸酯（I）}
7. Photocatalytic CC Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II) [O] . -1

机译：用混合价铜（I）/铜（I）的光催化CC从二氧化碳上减少氧化铜（I）/铜（II）
8. The Interaction of Hydrazine with Copper(II) Chloride in Acidic Solutions. The Formation, Spectral and Magnetic Properties, and Structures of Copper(II), Copper(I), and Mixed Valence Species. [R] . Brown, D. B., Donner, J. A., Hall, J. W., 1979

机译：肼与氯化铜（II）在酸性溶液中的相互作用。铜（II），铜（I）和混合价物种的形成，光谱和磁性以及结构。

In situ assembly of a host-guest linked, mixed valence copper(II)-copper(I) coordination polymer [Cu(l,2-en)_2μ_3-I)_2Cu_2(μ_2-I)_2]_n via partial reduction of copper(II) under ambient conditions

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