Syntheses, structures, magnetic, and luminescent properties of five lanthanide-based MOFs with p-phenylenediamine-tetraacetic acid ligand

Yu Meihui; Wang Xiubo; Hu Ming

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Syntheses, structures, magnetic, and luminescent properties of five lanthanide-based MOFs with p-phenylenediamine-tetraacetic acid ligand

机译：五种具有对苯二胺四乙酸配体的镧系元素MOF的合成，结构，磁性和发光性质

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Five new isomorphous metal-organic frameworks, {[Ln(PhDTA)(0.5)(H(2)PhDTA)(0.5)(H2O)(3)]H2O}(n) [Ln=Pr (1), Sm (2), Eu (3), Gd (4), Tb (5)], have been synthesized under solvothermal conditions based on p-phenylenediamine-N,N,N,N-tetraacetic acid (H(4)PhDTA). Compounds 1-5 were characterized by infrared spectra, thermogravimetric analyses and single-crystal X-ray diffraction. Compounds 1-5 crystallize in the monoclinic system with space group of P2(1)/c and have 3-D framework structures. The H(2)PhDTA(2-) and H(2)PhDTA(4-) ions exhibit different tetradentate and bidentate modes to connect with lanthanide ions, respectively. The solid-state luminescence of 5 and magnetism of 4 were investigated further.

机译：五个新的同构金属有机骨架，{[Ln（PhDTA）（0.5）（H（2）PhDTA）（0.5）（H2O）（3）] H2O}（n）[Ln = Pr（1），Sm（2 ），Eu（3），Gd（4），Tb（5）]是在溶剂热条件下基于对苯二胺-N，N，N，N-四乙酸（H（4）PhDTA）合成的。通过红外光谱，热重分析和单晶X射线衍射表征化合物1-5。化合物1-5在单斜晶系体系中具有P2（1）/ c的空间群结晶，并具有3-D骨架结构。 H（2）PhDTA（2-）和H（2）PhDTA（4-）离子分别显示不同的四齿和双齿模式以与镧系离子连接。进一步研究了5的固态发光和4的磁性。

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《Journal of Coordination Chemistry》 |2015年第4期|共9页
作者
Yu Meihui; Wang Xiubo; Hu Ming;
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正文语种 eng
中图分类无机化学;
关键词
Lanthanide; p-Phenylenediamine-N; N; N '; N '-tetraacetic acid; Luminescence; Magnetic property;

机译：镧系;对苯二胺-N;N;N';N'-四乙酸;发光;磁性;

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1. Syntheses, structures, magnetic, and luminescent properties of five lanthanide-based MOFs with p-phenylenediamine-tetraacetic acid ligand [J] . Yu Meihui, Wang Xiubo, Hu Ming Journal of Coordination Chemistry . 2015,第3a4期

机译：五种具有对苯二胺四乙酸配体的镧系元素MOF的合成，结构，磁性和发光性质
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Syntheses, structures, magnetic, and luminescent properties of five lanthanide-based MOFs with p-phenylenediamine-tetraacetic acid ligand

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