Fluoroalldy lation of aromatic compounds wiht per(poly)fluoroalkyl chlorides initiated by sodium dithionite in DMSO

Xiao-Ting Huang; Zheng-Yu Long; Qing-Yun Chen

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Fluoroalldy lation of aromatic compounds wiht per(poly)fluoroalkyl chlorides initiated by sodium dithionite in DMSO

机译：DMSO中连二亚硫酸钠引发的全（聚）氟代烷基氯与芳族化合物的氟代烷基化反应

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摘要

Treatment of electron-rich aromatic and heteroaromatic compounds with per(poly)fluoroalkyl chlorides in the presence of sodium dithionite in DMSO gives the corresponding fluoroalkylated products in moderate to good yields. The structures and yields of products depend mainly on the position and electron-donating ability of the substituents on the aromatic compounds.

机译：在DMSO中，在连二亚硫酸钠存在下，用全（聚）氟代烷基氯处理富电子芳族和杂芳族化合物，得到相应的氟代烷基化产物，产率中等至良好。产物的结构和产率主要取决于芳族化合物上取代基的位置和给电子能力。

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《Journal of Fluorine Chemistry》 |2001年第2期|共7页
作者
Xiao-Ting Huang; Zheng-Yu Long; Qing-Yun Chen;
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正文语种 eng
中图分类化学;
关键词
per(poly)fluoroalkyl chlorides; aromatic; fluoroalkylation;

机译：全（聚）氟代烷基氯;芳族;氟代烷基化;

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专利

1. Fluoroalldy lation of aromatic compounds wiht per(poly)fluoroalkyl chlorides initiated by sodium dithionite in DMSO [J] . Xiao-Ting Huang, Zheng-Yu Long, Qing-Yun Chen Journal of Fluorine Chemistry . 2001,第2期

机译：DMSO中连二亚硫酸钠引发的全（聚）氟代烷基氯与芳族化合物的氟代烷基化反应
2. Sodium Dithionite Initiated Addition-lactonization of 2-Acyl- amino-4-pentenoic Acids with Fluoroalkyl Iodides to Synthesize 4-Fluoroalkyl-2-acylamino-4-butyrolactones [J] . Xueyan Yang, Dr. Xianjin Yang, Shengjie Zhu, Chinese Journal of Chemistry . 2010,第11期

机译：连二亚硫酸钠引发的2-酰基-氨基-4-戊烯酸与氟代烷基碘的加成内酯合成4-氟代烷基-2-酰基氨基-4-丁内酯
3. Sodium Dithionite Initiated Addition-lactonization of 2-Acylamino-4-pentenoic Acids with Fluoroalkyl lodides to Synthesize 4-Fluoroalkyl-2-acylamino-4-butyrolactones [J] . Yang,Xueyan, Yang,Xianjin, Zhu,Shengjie, 中国化学（英文版） . 2010,第011期
4. STUDY OF WELL ALIGNED CONTINUOUS ELECTROSPUN NANOFIBERS OF POLY (AMIDE-COIMIDE)/POLY (TRIMELLITIC ANHYDRIDE CHLORIDE-CO-4, 4'-METHYLENEDIANILINE) USING SOLVENT MIXTURE OF DMSO/THF [C] . B. Bajaj, S. H. Lee, J. H. Kim, International Conference on Composite Materials . 2011

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Fluoroalldy lation of aromatic compounds wiht per(poly)fluoroalkyl chlorides initiated by sodium dithionite in DMSO

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