Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 2: screening immobilized metal complexes for catalytic activity.

Brase S; Dahmen S; Lauterwasser F; Leadbeater NE; Sharp EL

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Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 2: screening immobilized metal complexes for catalytic activity.

机译：聚合物结合的1-芳基-3-烷基三氮烯作为模块化配体进行催化。第2部分：筛选固定化的金属络合物的催化活性。

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A range of polymer-supported triazenes and their metal-bound analogues were screened for use in catalysis. Fe, Cu and Zr complexes were, together with the polymer-supported triazene ligand alone, screened in the addition of Et(2)Zn to benzaldehyde. A supported Pd triazene complex was screened for activity in Suzuki and Sonogashira reactions and a supported Ru triazene complex screened for transfer hydrogenation.

机译：筛选了一系列聚合物负载的三氮烯及其与金属结合的类似物以用于催化。 Fe，Cu和Zr配合物与单独的聚合物支持的三氮烯配体一起在向苯甲醛中添加Et（2）Zn时进行了筛选。针对Suzuki和Sonogashira反应，对负载的Pd三氮烯配合物进行了筛选，并针对转移氢化筛选了负载的Ru三氮烯配合物。

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来源
《Bioorganic and Medicinal Chemistry Letters》 |2002年第14期|共3页
作者
Brase S; Dahmen S; Lauterwasser F; Leadbeater NE; Sharp EL;
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正文语种 eng
中图分类药学;生物化学;
关键词
Organometallic Compounds; Polymers; Triazenes; Amines; Benzaldehydes; Diazonium Compounds; 有机金属化合物; 聚合物; 三氮烯;

机译：Organometallic Compounds;Polymers;Triazenes;Amines;Benzaldehydes;Diazonium Compounds;有机金属化合物;聚合物;三氮烯;

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1. Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 2: screening immobilized metal complexes for catalytic activity. [J] . Brase S, Dahmen S, Lauterwasser F, Bioorganic and Medicinal Chemistry Letters . 2002,第14期

机译：聚合物结合的1-芳基-3-烷基三氮烯作为模块化配体进行催化。第2部分：筛选固定化的金属络合物的催化活性。
2. Metallomicellar catalysis. Effects of bridge-connecting Ligands on the hydrolysis of PNPP catalyzed by Zn(II), Co(II), and Ni(II) complexes of ethoxyl-diamine ligands in micellar solution [J] . Fubin J., Bingying J., Xiaoqi Y., Langmuir: The ACS Journal of Surfaces and Colloids . 2002,第18期

机译：金属硅化物催化。桥联配体对胶束溶液中乙氧基二胺配体的Zn（II），Co（II）和Ni（II）配合物催化的PNPP水解的影响
3. Enantioselective catalysis. Part 148: Carbohydrate-derived oxime ethers stable towards hydrolysis-syntheses of ligands and complexes and a study of their catalytic properties [J] . Brunner H., Schonherr M., Zabel M. Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2003,第9期

机译：对映选择性催化。第148部分：对配体和配合物水解合成稳定的碳水化合物衍生的肟醚及其催化性能的研究
4. Development of Robust Metal Complexes Using Immobilized Chiral 2,2’-Bipyridine Ligand for Enantioselective Reactions in Water [C] . Fangqiu LU, Taku KITANOSONO, Shu KOBAYASHI 日本化学会春季年会講演予稿集 . 2018

机译：使用固定的手性2,2'-硼吡啶配体进行鲁棒金属配合物的开发在水中对映选择性反应进行映选择性反应
5. CATALYTIC HYDROGENATIONS AND HYDROFORMYLATIONS USING TRANSITION METAL CLUSTERS AND POLYMER-BOUND RUTHENIUM COMPLEXES. [D] . WILEMON, GARY MICHAEL. 1980

机译：使用过渡金属簇和聚合物键合的钌络合物的催化加氢和加氢甲酰化反应。
6. Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H2 formation with FeFe hydrogenase model complexes [O] . Alexander Aster, Shihuai Wang, Mohammad Mirmohades, 2019

机译：金属与配体的质子化以及氮杂二硫代盐配体在FeFe氢化酶模型配合物催化H2形成中的质子穿梭作用
7. Catalytic Outlooks of the Metal Complexes Formed with Nitrogen-Containing Macrocyclic Compounds as Ligand.IV : Catalytic Oxidations of Thiols with Molecular Oxygen in the Presence of Tetraaza 14 annulene-Cobalt (II) and Schiff-Base-Cobalt (II) Complexes [O] . 橋本守, 立藤幸博, 和田茂, 1985

机译：以含氮大环化合物作为配体形成的金属配合物的催化前景
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 2: screening immobilized metal complexes for catalytic activity.

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