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首页> 外文期刊>Journal of industrial and engineering chemistry >Effect of oxygen capacity and oxygen mobility of supported Mg3(VO4)2 catalysts on the performance in the oxidative dehydrogenation of n-butane
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Effect of oxygen capacity and oxygen mobility of supported Mg3(VO4)2 catalysts on the performance in the oxidative dehydrogenation of n-butane

机译:Mg3(VO4)2负载型催化剂的氧容量和氧迁移率对正丁烷氧化脱氢性能的影响

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摘要

Vanadium-magnesium oxide (Mg3(VO4)2) catalysts supported on Al2O3, ZrO2, MgO, and CeO2 were prepared by a wet impregnation method, and they were applied to the oxidative dehydrogenation of n-butane. Effect of oxygen capacity and oxygen mobility of supported Mg3(VO4)2 catalysts on the catalytic performance in the oxidative dehydrogenation of n-butane was investigated. Experimental results revealed that large oxygen capacity of the catalyst was favorable for obtaining high catalytic activity at the initial stage of reaction, while facile oxygen mobility of the catalyst led to stable catalytic activity during the catalytic reaction in the oxidative dehydrogenation of n-butane.
机译:通过湿式浸渍法制备了负载在Al2O3,ZrO2,MgO和CeO2上的钒镁氧化物(Mg3(VO4)2)催化剂,并将其用于正丁烷的氧化脱氢。研究了负载型Mg3(VO4)2催化剂的氧容量和氧迁移率对正丁烷氧化脱氢催化性能的影响。实验结果表明,催化剂的大氧气容量有利于在反应初期获得较高的催化活性,而催化剂的易移动性导致正丁烷氧化脱氢催化反应过程中的稳定催化活性。

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