首页> 外文期刊>Journal of industrial and engineering chemistry >Removal of Pb(II) from aqueous solution using ethylene diamine tetra acetic acid-Zr(IV) iodate composite cation exchanger: Kinetics, isotherms and thermodynamic studies
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Removal of Pb(II) from aqueous solution using ethylene diamine tetra acetic acid-Zr(IV) iodate composite cation exchanger: Kinetics, isotherms and thermodynamic studies

机译:使用乙二胺四乙酸-碘化锆(IV)复合阳离子交换剂从水溶液中去除铅(II):动力学,等温线和热力学研究

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摘要

EDTA-Zr(IV) iodate was prepared via the incorporation of-aqueous solution of EDTA into the inorganic precipitate of Zr(IV) iodate. Distribution coefficient values for different metals showed that EDTA-Zr(IV) iodate had the highest adsorption capacity for Pb(II). The practical applicability of EDTA-Zr(IV) iodate was explored by separating Pb(II) metal from a synthetic mixture of metal ions. Dependence of adsorption on contact time, pH of the solution, exchanger dose and temperature was studied to achieve the optimum conditions. Kinetic studies showed better applicability for pseudo-second-order model. Thermodynamic parameters viz. - entropy change, enthalpy change and Gibb's free energy change were also calculated. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
机译:EDTA-碘酸锆(IV)是通过将EDTA水溶液掺入碘酸锆(IV)的无机沉淀物中制备的。不同金属的分布系数值表明,EDTA-Zr(IV)碘酸盐对Pb(II)的吸附能力最高。通过从金属离子的合成混合物中分离出Pb(II)金属,探索了碘酸EDTA-Zr(IV)的实际适用性。研究了吸附对接触时间,溶液pH,交换剂剂量和温度的依赖性,以达到最佳条件。动力学研究表明,伪二阶模型具有更好的适用性。热力学参数,即。 -还计算了熵变化,焓变化和吉布的自由能变化。 (C)2014大韩工业化学工程学会。由Elsevier B.V.发布。保留所有权利。

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