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Tandem mass spectrometry fragmentation of the protonated 2-(2-phenylethyl)chromones from Agarwood: Radical ions versus non-radical ions

机译:沉香质子化的2-(2-苯乙基)色酮的串联质谱碎片化:自由基离子与非自由基离子

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摘要

Agarwood, also known as 'chenxiang' in Chinese, is the fragrant resinous heartwood obtained from certain trees of the genus Aquilaria (Malvales: Thymelaeaceae). Being a highly valuable non-timber product from Asian tropical forests, agarwood is used for incenses, perfumes and traditional medicines. Studies showed that the chemical constituents of agarwood are sesquiterpenes, 2-(2-phenylethyl)chromones, aromatics, triterpenes, etc.[1,2] The most abundant constituents in agarwood have been found to be 2-(2-phenylethyl)chromones (41%) and sesquiterpenes (52%).[1] Among which, 2-(2-phenylethyl)chromones are considered to be the major group of constituents responsible for the quality of agarwood and were found to possess neuroprotective,[3] cytotoxic,[4,5] antiallergic activities,[6] etc. It is obvious that detection and structure characterization of the main constituent, 2-(2-phenylethyl)chromones are key to the qualification of agarwood.
机译:沉香,在中文中也被称为“沉香”,是从沉香(Malvales:Thymelaeaceae)属的某些树木中获得的芳香树脂心材。沉香是来自亚洲热带森林的极有价值的非木材产品,沉香被用于熏香,香水和传统药物。研究表明,沉香的化学成分是倍半萜,2-(2-苯基乙基)色酮,芳香族化合物,三萜烯等。[1,2]沉香中最丰富的成分是2-(2-苯基乙基)色酮。 (41%)和倍半萜(52%)。[1]其中2-(2-苯乙基)色酮被认为是影响沉香质量的主要成分,并被发现具有神经保护作用,[3]细胞毒性,[4,5]抗过敏活性,[6]等很明显,主要成分2-(2-苯乙基)色酮的检测和结构表征是沉香木鉴定的关键。

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